High-temperature tensile properties of unmodified A356 alloy with and without the addition of Ni or V in traces (600 and 1000 ppm of Ni and V, respectively) were investigated by analyzing samples obtained from sand and permanent mold castings in the as-cast and T6 heat-treated conditions. Tensile tests were performed at 508 K (235°C) at a crosshead speed of 1 mm/min. In addition, samples were subjected to artificial aging at 508 K (235°C) for different times, and corresponding hardness curves were plotted. Microstructures and fracture surfaces, analyzed by FEG-SEM equipped with energy dispersive X-ray spectroscopy, showed that neither Ni nor V addition had a detrimental effect on high-temperature tensile properties. Aging curves showed a strong loss of hardness affecting the T6 class between 30-min and 1-h exposure time. After 6-h aging, no evidence of aging treatment persisted on hardness of the tested material. Hardness values did not reveal any significant difference between the reference alloy and the Ni-and V-containing alloys in both casting conditions, in complete analogy with the tensile properties. Unmodified eutectic silicon particles provided inhomogeneity in the a-Al matrix and acted as the principal source of stress concentration leading to fracture.
In this study, the effect of aging on the mechanical properties of unmodified A356 aluminium casting alloy with trace additions of Ni or V was investigated. Trace elements were added in concentrations of 600 and 1000 ppm of Ni and V, respectively. Samples from sand and permanent mould castings in as cast and T6 heat-treated conditions were tested. Tensile tests were performed at both room and high temperature (235 °C). Taking into account the results from both testing conditions, Vickers hardness was measured in order to endorse the hypothesis of artificial aging occurring during high temperature tensile tests. In order to study this effect, a series of specimens was aged at 235 °C for different aging times, and aging curves were plotted. The occurrence of static and dynamic aging was evaluated by comparing hardness values of tensile specimens and aged samples, particularly in the range of 5-20 min, as this range corresponds to the time necessary for pre-heating and testing of the tensile samples. A basic correlation between tensile strength and hardness is also given.
e present work investigates a narrow range of secondary dendrite arm spacing (SDAS), in an as-cast A356 alloy with and without copper (Cu) additions. Cu was added to the base A356 alloy melt to reach the target concentration of 0.5 and 1 wt.%. Samples were selected from 3 different positions within the cast plate, offering 30, 35, and 40 μm SDAS variants. Tensile curves revealed a strong influence between the specimen cutting position and strength, with a pronounced effect in the Cu-containing alloys. Hardness measurements did not confirm the tensile response; hence, to understand the phenomenon, microstructural features have been investigated in detail. Eutectic silicon (Si) particle equivalent diameter (ED) size decreased from the top (T) to the bottom (B) position of the cast. Eutectic Si particle surface area (A%) was found to be denser at the B as compared to the T and simultaneously in the Cu-containing alloy as compared to the Cu-free reference alloy. Backscattered electron (BSE) images were employed to investigate the nature of the Cu-rich intermetallic phases. In conclusion, electrical conductivity measurements were performed to confirm the trends observed.
In recent years, the influence of Ni on high-temperature mechanical properties of casting Al alloys has been extensively examined in the literature. In the present study, room temperature mechanical properties of an A356 alloy with Ni additions from 0.5 to 2 wt % were investigated. The role of Ni-based compounds and eutectic Si particles in reinforcing the Al matrix was studied with image analysis and was then related to tensile properties and microhardness. In the as-cast condition, the formation of the 3D network is not sufficient to determine an increase of mechanical properties of the alloys since fracture propagates by cleavage through eutectic Si particles and Ni aluminides or by the debonding of brittle phases from the aluminum matrix. After T6 heat treatment the increasing amount of Ni aluminides, due to further addition of Ni to the alloy, together with their brittle behavior, leads to a decrease of yield strength, ultimate tensile strength, and Vickers microhardness. Despite the fact that Ni addition up to 2 wt % hinders spheroidization of eutectic Si particles during T6 heat treatment, it also promotes the formation of a higher number of brittle Ni-based compounds that easily promote fracture propagation.
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