To constrain the formation history of an exoplanet, we need to know its chemical composition. With an equilibrium temperature of about 4,050 kelvin, the exoplanet KELT-9b (also known as HD 195689b) is an archetype of the class of ultrahot Jupiters that straddle the transition between stars and gas-giant exoplanets and are therefore useful for studying atmospheric chemistry. At these high temperatures, iron and several other transition metals are not sequestered in molecules or cloud particles and exist solely in their atomic forms. However, despite being the most abundant transition metal in nature, iron has not hitherto been detected directly in an exoplanet because it is highly refractory. The high temperatures of KELT-9b imply that its atmosphere is a tightly constrained chemical system that is expected to be nearly in chemical equilibrium and cloud-free, and it has been predicted that spectral lines of iron should be detectable in the visible range of wavelengths. Here we report observations of neutral and singly ionized atomic iron (Fe and Fe) and singly ionized atomic titanium (Ti) in the atmosphere of KELT-9b. We identify these species using cross-correlation analysis of high-resolution spectra obtained as the exoplanet passed in front of its host star. Similar detections of metals in other ultrahot Jupiters will provide constraints for planetary formation theories.

We present an open-source retrieval code named HELIOS-RETRIEVAL, designed to obtain chemical abundances and temperature-pressure profiles from inverting the measured spectra of exoplanetary atmospheres. We use an exact solution of the radiative transfer equation, in the pure absorption limit, in our forward model, which allows us to analytically integrate over all of the outgoing rays. Two chemistry models are considered: unconstrained chemistry and equilibrium chemistry (enforced via analytical formulae). The nested sampling algorithm allows us to formally implement Occam's Razor based on a comparison of the Bayesian evidence between models. We perform a retrieval analysis on the measured spectra of the four HR 8799 directly imaged exoplanets. Chemical equilibrium is disfavored for HR 8799b and c. We find supersolar C/H and O/H values for the outer HR 8799b and c exoplanets, while the inner HR 8799d and e exoplanets have a range of C/H and O/H values. The C/O values range from being superstellar for HR 8799b to being consistent with stellar for HR 8799c and being substellar for HR8799d and e. If these retrieved properties are representative of the bulk compositions of the exoplanets, then they are inconsistent with formation via gravitational instability (without late-time accretion) and consistent with a core accretion scenario in which late-time accretion of ices occurred differently for the inner and outer exoplanets. For HR 8799e, we find that spectroscopy in the K band is crucial for constraining C/O and C/H. HELIOS-RETRIEVAL is publicly available as part of the Exoclimes Simulation Platform (ESP; www.exoclime.org).

We present an improved, hybrid CPU-GPU atmospheric retrieval code, Helios-r.2, which is applicable to medium-resolution emission spectra of brown dwarfs, in preparation for precision atmospheric spectroscopy in the era of the James Webb Space Telescope. The model is available as open source code on the Exoclimes Simulation Platform. We subject Helios-r.2 to a battery of tests of varying difficulty. The simplest test involves a mock retrieval on a forward model generated using the same radiative transfer technique, the same implementation of opacities, and the same chemistry model. The least trivial test involves a mock retrieval on synthetic spectra from the Sonora model grid, which uses a different radiative transfer technique, a different implementation of opacities, and a different chemistry model. A calibration factor, which is included to capture uncertainties in the brown dwarf radius, distance to the brown dwarf and flux calibration of the spectrum, may compensate, sometimes erroneously, for discrepancies in modeling choices and implementation. We analyze spectra of the benchmark brown dwarf GJ 570 D and the binary brown dwarf companions in the Epsilon Indi system. The retrieved surface gravities are consistent with previous studies and/or values inferred from dynamical masses (for Epsilon Indi Ba and Bb only). There remains no clear criterion on how to reject unphysical values of the retrieved brown dwarf radii. The retrieved carbon-to-oxygen ratios and metallicity depend on whether chemical equilibrium is assumed.

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At optical wavelengths, Titan's brightness for large Sun-Titan-observer phase angles significantly exceeds its dayside brightness. The brightening that occurs near back-illumination is due to moderately large haze particles in the moon's extended atmosphere that forward-scatter the incident sunlight. Motivated by this phenomenon, here we investigate the forward scattering from currently known exoplanets, its diagnostics possibilities, the observational requirements to resolve it, and potential implications. An analytical expression is derived for the amount of starlight forward-scattered by an exponential atmosphere that takes into account the finite angular size of the star. We use this expression to tentatively estimate how prevalent this phenomenon may be. Based on numerical calculations that consider exoplanet visibility, we identify numerous planets with predicted out-of-transit forward scattering signals of up to tens of parts-per-million provided that aerosols of 1 µm size form over an extended vertical region near the optical radius level. We propose that the interpretation of available optical phase curves should be revised to constrain the strength of this phenomenon that might provide insight into aerosol scale heights and particle sizes. For the relatively general atmospheres considered here, forward scattering reduces the transmission-only transit depth by typically less than the equivalent to a scale height. For short-period exoplanets the finite angular size of the star severely affects the amount of radiation scattered towards the observer at mid-transit.