The associations found in this study reflect that several PM constituents, originating from different sources, may drive previously reported results between PM and hospital admissions in the Mediterranean area.
A study of the chemical composition of atmospheric particulate matter has been carried out in the city of Delhi. During two 6-day special observation periods, in November 2009 and in March 2010, we have determined atmospheric concentration of element, ions, elemental carbon, organic carbon and levoglucosan, obtaining a satisfactory mass closure (better than 94%). The results show that during these periods, pollutants produced by combustion sources constituted 6-7% of the total mass, and that the rest of it, in the absence of desert storms, was evenly divided among species coming from the soil, inorganic secondary compounds formed in the atmosphere and organic species. The results of the analysis of levoglucosan concentration showed that during the cold season in the atmosphere of Delhi about one fifth of the organics was directly produced by biomass burning. Elemental content of PM10 has also been determined once a week during the year 2008. It has been found that PM10 composition varies according to the season: soil components increase during the summer while secondary pollutants and organics increase during the post-monsoon and the winter. Elemental and ionic content of PM10 and PM2.5 have been determined every day during the week of Diwali festivals in 2008 and 2009. PM10 concentration has reached the value of 767 mu g m(-3) in 2008 and 620 mu g m(-3) in 2009; a remarkable increase of elements produced by firework combustion (Sr, Ba, Ti, Mg, Cu, K, S, V, Cl, Bi, Ga) has been detected. The analysis of the extractable and residual fraction of elements has shown that most of the elements were predominantly in the residual fraction and that changes in the size and solubility distribution occurred as a consequence of fireworks. (C) Author(s) 2011. This work is distributed under the Creative Commons Attribution 3.0 License
The seasonal variability in the mass concentration and chemical composition of atmospheric particulate matter (PM10 and PM2.5) was studied during a 2-year field study carried out between 2010 and 2012. The site of the study was the area of Ferrara (Po Valley, Northern Italy), which is characterized by frequent episodes of very stable atmospheric conditions in winter. Chemical analyses carried out during the study allowed the determination of the main components of atmospheric PM (macro-elements, ions, elemental carbon, organic matter) and a satisfactory mass closure was obtained. Accordingly, chemical components could be grouped into the main macro-sources of PM: soil, sea spray, inorganic compounds from secondary reactions, vehicular emission, organics from domestic heating, organics from secondary formation, and other sources. The more significant seasonal variations were observed for secondary inorganic species in the fine fraction of PM; these species were very sensitive to air mass age and thus to the frequency of stable atmospheric conditions. During the winter ammonium nitrate, the single species with the highest concentration, reached concentrations as high as 30 μg/m(3). The intensity of natural sources was fairly constant during the year; increases in natural aerosols were linked to medium and long-range transport episodes. The ratio of winter to summer concentrations was roughly 2 for combustion product, close to 3 for secondary inorganic species, and between 2 and 3 for organics. The winter increase of organics was due to poorer atmospheric dispersion and to the addition of the emission from domestic heating. A similar winter to summer ratio (around 3) was observed for the fine fraction of PM.
Abstract. The third intensive measurement period (IMP) organised by the European Monitoring and Evaluation Programme (EMEP) under the UNECE CLTRAP took place in summer 2012 and winter 2013, with PM10 filter samples concurrently collected at 20 (16 EMEP) regional background sites across Europe for subsequent analysis of their mineral dust content. All samples were analysed by the same or a comparable methodology. Higher PM10 mineral dust loadings were observed at most sites in summer (0.5–10 µg m−3) compared to winter (0.2–2 µg m−3), with the most elevated concentrations in the southern- and easternmost countries, accounting for 20–40 % of PM10. Saharan dust outbreaks were responsible for the high summer dust loadings at western and central European sites, whereas regional or local sources explained the elevated concentrations observed at eastern sites. The eastern Mediterranean sites experienced elevated levels due to African dust outbreaks during both summer and winter. The mineral dust composition varied more in winter than in summer, with a higher relative contribution of anthropogenic dust during the former period. A relatively high contribution of K from non-mineral and non-sea-salt sources, such as biomass burning, was evident in winter at some of the central and eastern European sites. The spatial distribution of some components and metals reveals the influence of specific anthropogenic sources on a regional scale: shipping emissions (V, Ni, and SO42−) in the Mediterranean region, metallurgy (Cr, Ni, and Mn) in central and eastern Europe, high temperature processes (As, Pb, and SO42−) in eastern countries, and traffic (Cu) at sites affected by emissions from nearby cities.
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