The article describes organic-rich rocks sequential extraction method for the bitumen composition difference. The method step-by-step extracts bitumen first from open and then from closed pores using three organic solvents with increasing polarity. The released bitumen differs in malthens/asphaltenes ratio, the distribution of n-alkanes, the content of terpanes and steranes, and, thus, the values of the biomarker parameters. These parameters show difference in the degree of organic matter thermal maturity, which is relates to different types of rock pore space. At the same time different parameters show different maturity ratio between bitumen from open and closed pores. Changes in the composition of bitumen allow to estimate the migration of hydrocarbon compounds through the well, to investigate the effect of sedimentation conditions on the pore space and the distribution of bitumen. The results show that investigation of bitumen received by one-step extraction from powder can lead to incorrect interpret of obtained results.
The article presents the results of hydrocarbon compounds extracted from open pores and blocked by resinous-asphaltene compounds pores in the Tutleim formation rocks (a stratigraphic analogue of the Bazhenov formation) and the underlying Jurassic deposits on the territory of the Kamennaya crest of the Krasnoleninsky arch investigation. The aim of the work was both to study the possible migration of hydrocarbons along the section and area and to assess the variability of the bitumen composition in rocks relative to the structural plan of the area of interest, along the section, as well as unconventional reservoirs. It is shown that the structural features and the assumed additional heating of the rocks lead to variety in the hydrocarbons composition not only in open, but also in blocked pores, both through the area of Tutleim formation distribution and in different intervals of one well. It was established that in the sediments organic matter, which may slightly differ in nature within the formation, can accumulate, and this leads to some differences in the generation, accumulation and migration of hydrocarbon compounds processes. It is shown that the process of migration of hydrocarbons from the underlying sediments also affects the bitumen composition in the rocks of the Tutleim formation.
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