The development of a photocatalyst with remarkable activity to degrade pollutants in aqueous and gas phase requires visible light-responsive stable materials, easily organized in the form of a thin layer (to exclude the highly expensive separation step). In this work, we present a one-step strategy for synthesizing material in the form of a self-organized TiO2/Ag2O nanotube (NT) array interlaced with silver nanoparticles (as in a cake with raisins) that exhibited photoactivity significantly enhanced compared to that of pristine TiO2 NTs under both ultraviolet (UV) and visible (vis) irradiation. An NT array composed of a mixture of TiO2 and Ag2O and spiked with Ag nanoparticles was formed via the anodization of a Ti–Ag alloy in a one-step reaction. Silver NPs have been formed during the in situ generation of Ag ions and were (i) embedded in the NT walls, (ii) stuck on the external NT walls, and (iii) placed inside the NTs. The enhancement of photocatalytic efficiency can be ascribed to the existence of an optimal content of Ag2O and Ag NPs, which are responsible for decreasing the number of recombination centers. In contrast to UV–vis light, performance improvement under vis irradiation occurs with increasing Ag2O and Ag0 contents in the TiO2/Ag2O/Ag NTs as a result of the utilization of larger amounts of incident photons. The optimized samples reached phenol degradation rates of 0.50 and 2.89 μmol dm–3 min–1 under visible and UV light, respectively, which means degradation activities 3.8- and 2-fold greater than that of the reference sample, respectively, remained after four photodegradation cycles under UV light.

No abstract

Vertically oriented, self-organized TiO2–MnO2 nanotube arrays were successfully obtained by one-step anodic oxidation of Ti–Mn alloys in an ethylene glycol-based electrolyte. The as-prepared samples were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), UV-Vis absorption, photoluminescence spectroscopy, X-ray diffraction (XRD), and micro-Raman spectroscopy. The effect of the applied potential (30–50 V), manganese content in the alloy (5–15 wt. %) and water content in the electrolyte (2–10 vol. %) on the morphology and photocatalytic properties was investigated for the first time. The photoactivity was assessed in the toluene removal reaction under visible light, using low-powered LEDs as an irradiation source (λmax = 465 nm). Morphology analysis showed that samples consisted of auto-aligned nanotubes over the surface of the alloy, their dimensions were: diameter = 76–118 nm, length = 1.0–3.4 μm and wall thickness = 8–11 nm. It was found that the increase in the applied potential led to increase the dimensions while the increase in the content of manganese in the alloy brought to shorter nanotubes. Notably, all samples were photoactive under the influence of visible light and the highest degradation achieved after 60 min of irradiation was 43%. The excitation mechanism of TiO2–MnO2 NTs under visible light was presented, pointing out the importance of MnO2 species for the generation of e− and h+.

TiO2/CuxOy nanotube (NT) arrays were synthesized using the anodization method in the presence of ethylene glycol and different parameters applied. The presence, morphology, and chemical character of the obtained structures was characterized using a variety of methods—SEM (scanning electron microscopy), XPS (X-ray photoelectron spectroscopy), XRD (X-ray crystallography), PL (photoluminescence), and EDX (energy-dispersive X-ray spectroscopy). A p-n mixed oxide heterojunction of Ti-Cu was created with a proved response to the visible light range and the stable form that were in contact with Ti. TiO2/CuxOy NTs presented the appearance of both Cu2O (mainly) and CuO components influencing the dimensions of the NTs (1.1–1.3 µm). Additionally, changes in voltage have been proven to affect the NTs’ length, which reached a value of 3.5 µm for Ti90Cu10_50V. Degradation of phenol in the aqueous phase was observed in 16% of Ti85Cu15_30V after 1 h of visible light irradiation (λ > 420 nm). Scavenger tests for phenol degradation process in presence of NT samples exposed the responsibility of superoxide radicals for degradation of organic compounds in Vis light region. Inactivation of bacteria strains Escherichia coli (E. coli), Bacillus subtilis (B. subtilis), and Clostridium sp. in presence of obtained TiO2/CuxOy NT photocatalysts, and Vis light has been studied showing a great improvement in inactivation efficiency with a response rate of 97% inactivation for E. coli and 98% for Clostridium sp. in 60 min. Evidently, TEM (transmission electron microscopy) images confirmed the bacteria cells’ damage.

Novel triple-layered trimetallic Au/Pd/Pt nanoparticles (NPs) with a porous Pt shell, showing a hedgehog-like structure, were successfully bounded with TiO2 and NaTaO3 surfaces, and used for photocatalytic purpose. To characterize all as-prepared samples, XRD, TEM, EDX, SEM, ISP-OES, DRS, XPS, and photoluminescence (PL) emission spectroscopy were applied. It was found that 25 nm Au/Pd/Pt core–shell NPs were formed, and good interaction between the porous Pt outer shells and the semiconductor surface was obtained. To appraise the effect of the semiconductor’s matrix type and the amount of used AuPdPt NPs on the photocatalytic performance, three types of reactions were employed: (i) degradation of phenol (under mono- and polychromatic irradiation), (ii) the efficiency of toluene removal in gas phase under visible light, and (iii) yield of H2 generation under UV–vis irradiation. Our results proved that the decoration of both TiO2 and NaTaO3 by AuPdPt NPs caused not only an increase in degradation yield of contaminants in the aqueous and gas phases but also significant enhancement in hydrogen generation. Amount of formed hydrogen was raised from 2.19 to 213.8 μmol/min for pristine rutile and rutile decorated by trimetallic NPs, respectively. In addition, the adsorption energy of water and oxygen molecules on modified TiO2_rutile and TiO2_anatase surface were investigated by the density functional (DFT) calculations. Data obtained by theoretical computation was found to be complementary to experimental results. In summary, the ternary metallic core–shell Au/Pd/Pt nanoparticles were successfully applied for TiO2 and NaTaO3 modification and resulted in providing new promising materials for the environmental purification and for production of alternative energy sources when irradiated under visible and UV–vis light.

A heterojunction with excellent visible light response and stability based on titanium dioxide nanotubes (TiO 2 NTs), bismuth sulfide quantum dots (Bi 2 S 3 QDs), and platinum nanoparticles (Pt NPs) is proposed. Both Pt NPs (3.0 ± 0.2 nm) and Bi 2 S 3 QDs (3.50 ± 0.20 nm) are well distributed on the (i) top parts, (ii) inner walls, and (iii) outer walls of the TiO 2 NTs. Visible-light-induced photoreaction was initialized by excitation of narrow band gap Bi 2 S 3 QDs, followed by electron injection to the conduction band of TiO 2 , while Pt NPs acted as electron traps, enhacing O 2 −• generation. Phenol in the aqueous phase and toluene in the gas phase were efficiently degraded over Bi 2 S 3 −Pt NTs, even for wavelengths longer than 455 and 465 nm, respectively, while no degradation of model compounds was observed over pristine TiO 2 NTs under the same irradiation conditions. Photocatalytic tests of phenol degradation in the presence of scavengers revealed that superoxide radicals were responsible for the visible-light degradation of organic compounds in the aqueous phase.

V2O5-TiO2 mixed oxide nanotube (NT) layers were successfully prepared via the one-step anodization of Ti-V alloys. The obtained samples were characterized by scanning electron microscopy (SEM), UV-Vis absorption, photoluminescence spectroscopy, energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (DRX), and micro-Raman spectroscopy. The effect of the applied voltage (30–50 V), vanadium content (5–15 wt %) in the alloy, and water content (2–10 vol %) in an ethylene glycol-based electrolyte was studied systematically to determine their influence on the morphology, and for the first-time, on the photocatalytic properties of these nanomaterials. The morphology of the samples varied from sponge-like to highly-organized nanotubular structures. The vanadium content in the alloy was found to have the highest influence on the morphology and the sample with the lowest vanadium content (5 wt %) exhibited the best auto-alignment and self-organization (length = 1 μm, diameter = 86 nm and wall thickness = 11 nm). Additionally, a probable growth mechanism of V2O5-TiO2 nanotubes (NTs) over the Ti-V alloys was presented. Toluene, in the gas phase, was effectively removed through photodegradation under visible light (LEDs, λmax = 465 nm) in the presence of the modified TiO2 nanostructures. The highest degradation value was 35% after 60 min of irradiation. V2O5 species were ascribed as the main structures responsible for the generation of photoactive e− and h+ under Vis light and a possible excitation mechanism was proposed.

No abstract