It has been shown that the foliar application of inorganic nano-materials on cereal plants during their growth cycle enhances the rate of plant productivity by providing a micro-nutrient source. We therefore studied the effects of foliarly applied ZnO nanoparticles (ZnO NPs) on Setaria italica L. foxtail millet’s quantitative, nutritional, and physiological parameters. Scanning electron microscopy showed that the ZnO NPs have an average particle size under 20 nm and dominant spherically shaped morphology. Energy dispersive X-ray spectrometry then confirmed ZnO NP homogeneity, and X-ray diffraction verified their high crystalline and wurtzite-structure symmetry. Although plant height, thousand grain weight, and grain yield quantitative parameters did not differ statistically between ZnO NP-treated and untreated plants, the ZnO NP-treated plant grains had significantly higher oil and total nitrogen contents and significantly lower crop water stress index (CWSI). This highlights that the slow-releasing nano-fertilizer improves plant physiological properties and various grain nutritional parameters, and its application is therefore especially beneficial for progressive nanomaterial-based industries.

Nano-fertilisers have only recently been introduced to intensify plant production, and there still remains inadequate scientific knowledge on their plant-related effects. This paper therefore compares the effects of two nano-fertilisers on common sunflower production under field conditions. The benefits arising from the foliar application of micronutrient-based zinc oxide fertiliser were compared with those from the titanium dioxide plant-growth enhancer. Both the zinc oxide (ZnO) and titanium dioxide (TiO2) were delivered by foliar application in nano-size at a concentration of 2.6 mg·L−1. The foliar-applied nanoparticles (NPs) had good crystallinity and a mean size distribution under 30 nm. There were significant differences between these two experimental treatments in the leaf surfaces’ trichomes diversity, ratio, width, and length at the flower-bud development stage. Somewhat surprisingly, our results established that the ZnO-NPs treatment induced generally better sunflower physiological responses, while the TiO2-NPs primarily affected quantitative and nutritional parameters such as oil content and changed sunflower physiology to early maturation. There were no differences detected in titanium or zinc translocation or accumulation in the fully ripe sunflower seeds compared to the experimental controls, and our positive results therefore encourage further nano-fertiliser research.

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ABSTRACT:Arsenic is a ubiquitous element in the environment and occurs naturally in both organic and inorganic forms. Under aerobic condition, the dominant form of arsenic in waters is arsenate, which is highly mobile and toxic. Arsenic poisoning from drinking water remains a serious world health issue. There are various standard methods for arsenic removal from drinking waters (coagulation, sorption, ion-exchange reactions or methods of reverse osmosis) and alternative methods, such as biosorption. Biosorption of arsenic from natural and model waters by native or chemically modified (with urea or ferric oxyhydroxides) plant biomass prepared from sawdust of Picea abies was studied. The kinetic of the adsorption process fitted well the pseudo second order adsorption model and equilibrium was achieved after 2 h. The results showed that biosorption was well described by both Langmuir and Freundlich isotherms. The maximum biosorption capacity of the sawdust modified with ferric oxyhydroxides, evaluated by Langmuir adsorption model, was 9.259 mg/g, while the biosorption capacity of unmodified biosorbent or biosorbent modified with urea was negligible. The adsorption capacity is comparable to results published by other authors, suggesting that the prepared chemically modified biosorbent has potential in remediation of contaminated waters.

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Recent studies show that biochar improves physical properties of soils and contributes to the carbon sequestration. In contrast to most other studies on biochar, the present study comprise a long-term field experiment with a special focus on the simultaneous impact of N-fertilizer to soil structure parameters and content of soil organic carbon (SOC) since SOC has been linked to improved aggregate stability. However, the question remains: how does the content of water-stable aggregates change with the content of organic matter? In this paper we investigate the effects of biochar alone and in a combination with N-fertilizer (i) on the content of water-stable macro- (WSAma) and micro-aggregates (WSAmi) as well as soil structure parameters; and (ii) on the contents of SOC and labile carbon (CL) in water-stable aggregates (WSA). A field experiment was conducted with different biochar application rates: B0 control (0 t ha−1), B10 (10 t ha−1) and B20 (20 t ha−1) and 0 (no N), 1st and 2nd level of nitrogen fertilization. The doses of level 1 were calculated on required average crop production using the balance method. The level 2 included an application of additional 100% of N in 2014 and additional 50% of N in the years 2015–2016 on silty loam Haplic Luvisol at the study site located at Dolná Malanta (Slovakia). The effects were investigated after the growing season of spring barley, maize and spring wheat in 2014, 2015 and 2016, respectively. The results indicate that the B10N0 treatment significantly decreased the structure vulnerability by 25% compared to B0N0. Overall, the lower level of N combined with lower doses of biochar and the higher level of N showed positive effects on the average contents of higher classes of WSAma and other soil structure parameters. The content of SOC in WSA in all size classes and the content of CL in WSAma 3–1 mm significantly increased after applying 20 t ha–1 of biochar compared to B0N0. In the case of the B20N1 treatment, the content of SOC in WSAma within the size classes >5 mm (8%), 5–3 mm (19%), 3–2 mm (12%), 2–1 mm (16%), 1–0.5 mm (14%), 0.5–0.25 mm (9%) and WSAmi (12%) was higher than in B0N1. We also observed a considerably higher content of SOC in WSAma 5–0.5 mm and WSAmi with the B10N1 treatment as compared to B0N1. Doses of 20 t biochar ha−1 combined with second level of N fertilization had significant effect on the increase of WSAma and WSAmi compared to the B0N2 treatment. A significant increase of CL in WSA was determined for size classes of 2–0.25 mm and WSAmi in the B20N2 treatment. Our findings showed that biochar might have beneficial effects on soil structure parameters, SOC, CL in WSA and carbon sequestration, depending on the applied amounts of biochar and nitrogen.

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