The legacy of the mining industry has left a large number of tailing ponds in the Cartagena–La Unión mining district exposed to water and wind erosion, which causes serious environmental and health problems and requires remediation. Before applying any remediation technique, an intensive sampling of the materials infilling the pond is required to determine the geochemistry of the pond, which will condition the remediation process. However, sampling the large number of tailing ponds that compose the district could be expensive. Thus, the main objective of this study is to evaluate the usefulness of electrical resistivity tomography (ERT) as a non-invasive tool to provide an image of spatial subsurface resistivity distribution and its relation to the physicochemical composition of near-surface mine wastes. To achieve this objective, three short ERT profiles were conducted, and 12 samples in each profile were collected at different depths for its geochemical characterization. Several non-linear regression models were fitted to predict physicochemical properties and metal concentrations from electrical resistivity measures. As a result, a high resistivity area was depicted in the ERT profiles G2 and G3, while the low resistivity ERT profile G1 was also obtained in accordance with the site’s surficial characteristics. Relationships among low resistivity values and high salinity, clay content, high metal concentrations, and mobility were established. Specifically, calibrated models were obtained for electrical conductivity, particle sizes of 0.02–50 µm and 50–2000 µm, total Zn and Cd concentration, and bioavailable Ni, Cd, and Fe. The ERT technique was shown to be a useful tool for the approximation of the location and distribution of the highest ranges of fine particle sizes, moisture, and, to a lesser extent, metal accumulation in the near-surface waste materials.
In Spain, livestock farming is a significant activity area that generates substantial revenues and essential jobs. However, the actual impact that this intensive activity might have on the environment is not entirely understood. Moreover, coastal aquifers are subjected to a significant environmental pressure due to nearby growing population, intensive agriculture, and livestock farming. In this work, three representative pig slurry ponds, under semiarid conditions, were studied using different techniques to evaluate the subsurface conditions in terms of pH, electrical conductivity, salts, and nitrate content. The electrical resistivity tomography (ERT) technique was employed in this study, which provides electrical resistivity values from the subsurface materials and fluids. These electrical resistivity values were compared to data obtained from geochemical analyses to derive their relationships and establish the pig slurry-affected subsurface area. Thus, ERT-based lower electrical resistivity values were associated with higher salts concentrations and nitrate content. ERT values indicated a near-surface affected by slurry infiltration that coincided with the increase of geochemical values obtained from sample analyses. Additionally, Spearman’s correlation was used to evaluate the correlation between electrical resistivity data and the physical-chemical properties of soil. The most important pollutant accumulation mainly occurs in the two-meter depth. Therefore, the risk of slurry ponds affecting deep aquifers is limited in the studied area. Finally, this study proves a complete, affordable, and scalable methodology application to livestock residue storage facilities.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.