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The occurrence of smectite-illite and smectite-chlorite minerals series was studied along a thick clay cap (~300 m) drilled in the Cerro Pabellón geothermal field (northern Andes, Chile). X-ray diffraction (XRD) and scanning electronic microscopy (SEM) were used to characterize the alteration mineralogy and clay mineral assemblages and their changes with depth. Cerro Pabellón is a high-enthalpy blind geothermal system, with a reservoir zone from ~500 m to 2000 m depth, with temperatures of 200–250°C. Three main hydrothermal alteration zones were identified: (1) argillic; (2) sub-propylitic, and (3) propylitic, with variable amounts of smectite, illite-smectite, chlorite-smectite, mixed-layer chlorite-corrensite, illite and chlorite appearing in the groundmass and filling amygdales and veinlets. Chemical and XRD data of smectites, I-S and illites show, with some exceptions, a progressive illitization with depth. The evolution of I-S with depth, shows a sigmoidal variation in the percentage of illite layers, with the conversion of smectite to R1 I-S at ~180–185°C. These temperatures are greater than those reported for other similar geothermal fields and might indicate, at least in part, the efficiency of the clay cap in terms of restricting the circulation of hydrothermal fluids in low-permeability rocks. Our results highlight the importance of a better understanding of clay-mineral evolution in active geothermal systems, not only as a direct (or indirect) way to control temperature evolution, but also as a control on permeability/porosity efficiency of the clay cap.

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In this work we assessed the shallow geothermal heat-exchange potential of a fluvial plain of the Central Apennines, the lower Metauro Valley, where about 90,000 people live. Publicly available geognostic drilling data from the Italian Seismic Microzonation studies have been exploited together with hydrogeological and thermophysical properties of the main geological formations of the area. These data have been averaged over the firsts 100 m of subsoil to define the thermal conductivity, the specific heat extraction rates of the ground and to establish the geothermal potential of the area (expressed in MWh y−1). The investigation revealed that the heat-exchange potential is mainly controlled by the bedrock lithotypes and the saturated conditions of the sedimentary infill. A general increase in thermal conductivity, specific heat extraction and geothermal potential have been mapped moving from the coast, where higher sedimentary infill thicknesses have been found, towards the inland where the carbonate bedrock approaches the surface. The geothermal potential of the investigated lower Metauro Valley is mostly between ~9.0 and ~10 MWh y−1 and the average depth to be drilled to supply a standard domestic power demand of 4.0 kW is ~96 m (ranging from 82 to 125 m all over the valley). This investigation emphasizes that the Seismic Microzonation studies represent a huge database to be exploited for the best assessment of the shallow geothermal potential throughout the Italian regions, which can be addressed by the implementation of heating and cooling through vertical closed-loop borehole heat exchanger systems coupled with geothermal heat pumps.

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