It is well established that at ambient and supercooled conditions water can be described as a percolating network of H bonds. This work is aimed at identifying, by neutron diffraction experiments combined with computer simulations, a percolation line in supercritical water, where the extension of the H-bond network is in question. It is found that in real supercritical water liquidlike states are observed at or above the percolation threshold, while below this threshold gaslike water forms small, sheetlike configurations. Inspection of the three-dimensional arrangement of water molecules suggests that crossing of this percolation line is accompanied by a change of symmetry in the first neighboring shell of molecules from trigonal below the line to tetrahedral above.
We present molecular dynamics simulations of a simple model for polymer melts with intramolecular barriers. We investigate structural relaxation as a function of the barrier strength. Dynamic correlators can be consistently analyzed within the framework of the mode coupling theory of the glass transition. Control parameters are tuned in order to induce a competition between general packing effects and polymer-specific intramolecular barriers as mechanisms for dynamic arrest. This competition yields unusually large values of the so-called mode coupling theory exponent parameter and rationalizes qualitatively different observations for simple bead-spring and realistic polymers. The systematic study of the effect of intramolecular barriers presented here also establishes a fundamental difference between the nature of the glass transition in polymers and in simple glass formers.
We present computer simulations of
concentrated solutions of unknotted
nonconcatenated semiflexible ring polymers. Unlike in their flexible
counterparts, shrinking involves a strong energetic penalty, favoring
interpenetration and clustering of the rings. We investigate the slow
dynamics of the centers-of-mass of the rings in the amorphous cluster
phase, consisting of disordered columns of oblate rings penetrated
by bundles of prolate ones. Scattering functions reveal a striking
decoupling of self- and collective motions. Correlations between centers-of-mass
exhibit slow relaxation, as expected for an incipient glass transition,
indicating the dynamic arrest of the cluster positions. However, self-correlations
decay at much shorter time scales. This feature is a manifestation
of the fast, continuous exchange and diffusion of the individual rings
over the matrix of clusters. Our results reveal a novel scenario of
glass formation in a simple monodisperse system, characterized by
self-collective decoupling, soft caging, and mild dynamic heterogeneity.
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