Bulk Zn1−xCoxO samples were synthesized via standard solid-state reaction route with different Co molar concentrations up to 21%. A detailed microstructural analysis was carried out to investigate alternative sources of ferromagnetism, such as secondary phases and nanocrystals embedded in the bulk material. Conjugating different techniques we confirmed the Zn replacement by Co ions in the wurtzite ZnO structure, which retains, however, a high crystalline quality. No segregated secondary phases neither Co-rich nanocrystals were detected. Superconducting quantum interference device magnetometry demonstrates a paramagnetic Curie–Weiss behavior with antiferromagnetic interactions. We discuss the observed room temperature paramagnetism of our samples considering the current models for the magnetic properties of diluted magnetic semiconductors.
Control of fine-structure splitting and excitonic binding energies in selected individual In As ∕ Ga As quantum dots Electric-field-induced anisotropy of excitonic optical properties in semiconductor quantum dots J. Appl. Phys. 94, 342 (2003); 10.1063/1.1578524
Study of excitonic ground state energies in coupled three-quantum dot systems for far-infrared laser applicationsThe authors have calculated the electronic structure for type-II InP / GaAs quantum dot systems considering a three-dimensional geometry including the wetting layer and the electron-hole interaction, which is the only responsible for the hole localization. Their results for the InP / GaAs structure show the electron confined inside the dot and the hole in the GaAs layer, partially above and below the dot. The authors propose structures with InGaAs or InGaP layers, where the hole wave function forms a ring around the dot walls. The electron-hole overlap, and therefore, the carrier lifetimes are very sensitive to the structural geometry, which is an important tool for device engineering.
We investigated structural and optical properties of type-II InP/GaAs quantum dots using reflection high energy electron diffraction, transmission electron microscopy, atomic force microscopy, grazing incidence x-ray diffraction, and photoluminescence techniques. The InP dots present an efficient optical emission even when they are uncapped, which is attributed to the low surface recombination velocity in InP. We compare the difference in the optical properties between surface free dots, which are not covered by any material, with dots covered by a GaAs capping layer. We observed a bimodal dispersion of the dot size distribution, giving rise to two distinct emission bands. The results also revealed that the strain accumulated in the InP islands is slightly relieved for samples with large InP amounts. An unexpected result is the relatively large blue shift of the emission band from uncapped samples as compared to capped dots.
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