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Magnetic systems exhibiting an exchange bias effect are being considered as materials for applications in data storage devices, sensors, and biomedicine. Because the size of new magnetic devices is being continuously reduced, the influence of thermally induced instabilities in magnetic order has to be taken into account during their fabrication process. In this study, we show the influence of superparamagnetism on the magnetic properties of an exchange-biased [CoO/Co/Pd] multilayer. We find that the process of progressive thermal blocking of the superparamagnetic clusters causes an unusually fast rise of the exchange anisotropy field and coercivity and promotes easy-axis switching to the out-of-plane direction.

Calcium phosphates offer outstanding biological adaptability. Thanks to their specific physico-chemical properties they are one of the most widely used materials in bone tissue engineering applications. The search for an innovative and economic strategy of synthesizing their different forms has been drawing considerable attention in the field. Herein, we report on a facile hydrothermal process in the presence of ethylenediamine tetraacetic acid and monoethanolamine to obtain various forms of calcium phosphates. The monoethanolamine served as an alkaline source and crystal growth modifier, while ethylenediamine tetraacetic acid was used to control the Ca2+ supersaturation level under high temperature and high pressure conditions. The obtained inorganic compounds were examined for their elemental composition, morphology, and structure using scanning electron microscopy, Raman spectroscopy, and powder x-ray diffraction. We were able to selectively synthesize monetite plate-like microcrystals as well as hydroxyapatite plates and nanofibers by simply varying the concentration of monoethanolamine.

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Magnetic nanostructures revealing exchange bias effect have gained a lot of interest in recent years due to their possible applications in modern devices with various functionalities. In this paper, we present our studies on patterned [CoO/Co/Pd] multilayer where ferromagnetic material is in a form of clusters, instead of being a continuous layer. The system was patterned using nanosphere lithography technique which resulted in creation of an assembly of well-ordered antidots or islands over a large substrate area. We found that the overall hysteresis loop of the films consists of hard and soft components. The hard component hysteresis loop exhibits a large exchange bias field up to -11 kOe. The patterning process causes a slight increase of the exchange field as the antidot radius rises. We also found that the material on edges of the structures gives rise to a soft unbiased magnetization component.