The chemical characteristics of the surface sediment (0-5 cm) in a lake which formed in an opencast sulphur mine in Southern Poland have been analysed. Generally, the concentration of major elements (N, P, S, Ca, K, Mg, Cl, Fe, Si, and Al) and trace elements (Ag, As, Ba, Cd, Co, Cr, Cu, Ga, Hg, I, Mn, Mo, Ni, Pb, Rb, Sr, Ti, Y, and Zn) in the lake sediment reflected the natural regional background. The sediment was characterised by low amounts of organic matter (LOI ca. 5%). MANOVA indicated that the concentrations of 60% of the elements differed significantly between transects and 32% with respect to depths, whereas seasonal differentiations were not found. The relationships between the studied elements calculated using factor analysis and correlation matrix are discussed. The bottom sediment show considerable heterogeneity, which is probably connected to their allochthonous origins and the young age of the lake.