The Borborema Pegmatitic Province (BPP), northeastern Brazil, is historically important for tantalum mining and also famous for top-quality specimens of exotic Nb-Ta oxides and, more recently, for the production of gem quality, turquoise blue, 'Paraíba Elbaite.' With more than 750 registered mineralized rare-element granitic pegmatites, the BPP extends over an area of about 75 by 150 km in the eastern part of the Neoproterozoic Seridó Belt. The Late Cambrian pegmatites are mostly hosted by a sequence of Neoproterozoic cordierite-sillimanite biotite schists of the Seridó Formation and quartzites and metaconglomerates of the Equador Formation. The trace-element ratios in feldspar and micas allow to classify most pegmatites as belonging to the beryl-columbite phosphate subtype. Electron microprobe analyses (EMPA) of columbite, tapiolite, niobiantantalian rutile, ixiolite and wodginite group minerals from 28 pegmatites in the BPP are used to evaluate the effectiveness of Nb-Ta oxide chemistry as a possible exploration tool, to trace the degree of pegmatite fractionation and to classify the pegmatites. The columbite group mineral composition allows to establish a compositional trend from manganoan ferrocolumbite to manganocolumbite and on to manganotantalite. This trend is typical of complex spodumene-and/or lepidolite-subtype pegmatites. It clearly contrasts with another trend, from ferrocolumbite through ferrotantalite to ferrowodginite and ferrotapiolite compositions, typical of pegmatites of the beryl-columbite phosphate subtype. Large scatter and anomalous trends in zoned crystals partially overlap and conceal the two main evolution patterns. This indicates that a large representative data set of heavy mineral concentrate samples, collected systematically along cross-sections, would be necessary to predict the metallogenetic potential of individual pegmatites. Other mineral species, e.g. garnets and/or tourmaline, with a more regular distribution than Nb-Ta oxides, would be more appropriate and less expensive for routine exploration purposes. The currently available Nb-Ta oxide chemistry data suggest the potential for highly fractionated Ta-Li-Cs pegmatites in the BPP, so far undiscovered, and encourages further, more detailed research.

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The Borborema pegmatite Province, NE-Brazil revisited

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The first occurrence of chrysoberyl in the Borborema Pegmatite Province (BPP) in northeastern Brazil is reported from up to 0.5 m large boulders in the dumps covering the Roncadeira pegmatite, worked in the 1940's for Sn-and Ta-ore concentrate. The chrysoberyl occurs in tabular, transparent light yellow crystals, up to two centimeters across. It is associated with quartz and fibrolitic sillimanite along centimeter-thick sigmoidal shear zones crosscutting banded sodic aplite facies of the pegmatite. Along the crystal borders, the chrysoberyl (Cbl) contains commonly small rounded inclusions of quartz and microscopic fibrous radial aggregates of sillimanite. A metamorphic-metasomatic origin of the chrysoberyl by the reaction Beryl + albite + muscovite + H + = chrysoberyl + quartz + sillimanite + Na + K + H 2 O, seems to be the most plausible to explain the observed textural relations. The origin of sillimanite + chrysoberyl + quartz under amphibolite-grade metamorphic conditions (~600 °C, 3.5 to 5 kbar) implies either an existence of a new generation of syn-metamorphic REL-pegmatites in the BPP or a late-tectonic recurrent increase in P-T conditions in the area. Another, less probable, alternative is a metastable formation of chrysoberyl and sillimanite at lower, retrometamorphic P-T conditions. The interaction of similar pegmatites known to occur south and north of Roncadeira with metabasic rock intercalations in the Seridó Formation opens the perspective for the finding of the gem-variety alexandrite in the BPP.

Auriferous quartz veins are known to exist in more than two dozen prospects, encompassing an area of 500 km 2 northward from Serrita township (state of Pernambuco) in northeastern Brazil. Gold-bearing veins occur either with a strike of 70° to 110°, crosscutting muscovite schists of the Middle Proterozoic Salgueiro Group, or with a strike of 330° in granodiorite intrusions in the same schists. Small amounts of pyrite, galena, arsenopyrite, chalcopyrite, and sphalerite commonly are observed. Sericite, chlorite, and epidote are the most common wallrock alteration products.Fluid inclusions were studied in samples of mineralized quartz veins from the Barra Verde III prospect in a small granodiorite body, and from the Ingá, Saburá, and Riacho do Meio prospects in the Salgueiro schists. Some samples of barren quartz veins also were studied for comparison.Primary and pseudosecondary inclusions in the mineralized veins are triphasic or biphasic aqueous-carbonic at room temperature. The wide range of the CO 2 /H 2 O volume ratio (between 2:1 and 1:3) in a single group or trail suggests the coexistence of two immiscible fluids during the penecontemporaneous processes of quartz crystallization, deformation, mineralization, and recrystallization. Total homogenization of these inclusions beginning at 290° to 310°C and 1.3 to 1.8 kbar provides the trapping conditions of the heterogeneous, effervescent fluid. CO 2 melting temperatures of ~-57° to -59°C indicate low CH 4 or N 2 contents. Clathrate melting close to 6.3°C indicates a low salinity of ~6.9% NaCl equiv. In addition, the low CH 4 content of the fluid in equilibrium with sulfides and alteration minerals suggests an oxygen fugacity between 10~3 0 and 10 27 , a total sulfur activity of 10 -2 to 10°, and a neutral pH of ~5.

Aerial gamma-ray survey data covering Neoproterozoic supracrustal sequences in the Seridó Belt were processed and analyzed together with ground gamma-ray data, air photos and geological data for lithogeophysical characterization and mapping of granitic rocks, related pegmatites fields and lithological units of Seridó Group. Interpretation was based on individual and ternary images of the three radio-elements and the eU/eTh and eTh/K ratios, and allowed the discovery of thorium anomalies associated with coarse-grained metarenites and metaconglomerates facies intercalated with quartzites of the Equador Formation. High contents of iron oxides, ilmenite, monazite, rutile, titanite and zircon were identified by ore microscopy of polished sections in the metaconglomerate's matrix. Semiquantitative scanning electron microscopy (SEM) analyses in minerals of two samples revealed up to 79.4% of ThO 2 and 87.7% of REE in monazites; up to 99.2% of TiO 2 in ilmenite and rutile and up to 1.81% of HfO 2 in zircon. Gamma-ray anomalies due to thorium were also identified in association with sediments of Cenozoic age in the region.RESUMO. Dados digitais de um aerolevantamento gamaespectrométrico cobrindo sequência crustal Neoproterozóica da Faixa Seridó (FSe) foram processados e analisados juntamente com medidas de gamaespectrometria terrestre, fotos aéreas e dados geológicos de campo, objetivando a caracterização e o mapeamento litogeofísico de granitos pegmatíticos e campos de pegmatitos associados, bem como de litologias e unidades litoestratigráficas do Grupo Seridó. A interpretação das imagens individuais e ternária dos canais do urânio (eU), do tório (eTh) e do potássio (K), além das razões eU/eTh e eTh/K, possibilitou a identificação de anomalias de tório associadas a metaconglomerados e metarenitos intercalados nos quartzitos da Formação Equador, constituídos de fragmentos e seixos de quartzo, muscovita e concentrações de minerais pesados, dominantemente hematita, ilmenita, monazita, rutilo, titanita e zircão. A análise semiquantitativa em grãos minerais de duas amostras dessas rochas, por microscopia de varredura eletrônica (MEV-EDS), revelou teores máximos de 79,4% de ThO 2 e 87,7% de ETR (Ce, La, Nd) em monazitas; 99,2% de TiO 2 em ilmenita e rutilo e 1,81% de HfO 2 em zircão. Também foram identificadas anomalias de tório em sedimentos de idade cenozóica na mesma região.