For an undisturbed operation of two-stage high-pressure fermentation up to 100 bar, a particle-free hydrolysate appears to be necessary. This is even more important if the second stage, i.e., the methane reactor, is designed as fixed bed. Here, we present the potential of microfiltration membranes as separation unit after the first stage, which is the hydrolysis. The study included the selection of membrane material, membrane performance investigations, and long-term-behavior during the filtration period. In a series of experiments, the optimum type of membrane material and the mode of operation [either crossflow (CF) or submerged (S)] were determined. Ceramic membranes proved to be the better option to treat the process stream due to their chemical and temperature resistance. The crossflow filtration achieved a sustainable flux of up to 33 L/(m h), while long-term experiments with the submerged membranes confirmed a critical flux of 7 L/(m h). Comparative analyses of hydrolysate and permeate showed that the rejected chemical oxygen demand (COD) as well as total organic carbon (TOC) fraction and thereby the loss of organic carbon in the permeate does not reduce the methane yield.
Cost-efficient operation of inland brackish water reverse osmosis (BWRO) demands a high recovery. As recovery of BWRO is often limited to scaling, antiscalants (AS) are applied, whose environmental impact is disputed. In this paper, different systems (conventional single-and two-stage plug flow RO (PFRO) and closed-circuit RO (CCRO)) were simulated in various configurations (AS dosing, ion exchange (IEX) pretreatment, elements per vessel) to determine the recovery limiting factor for a hard feed. The novel proposed IEX-CCRO reached the highest recovery without AS dosing. PFRO configurations had lower recoveries, mainly due to hydraulic limitations. Utilizing RO brine reduced both the water demand and salts necessary for IEX regeneration.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.