Abstract. The hydrogen isotopic composition (δ2H) of leaf waxes, especially of n-alkanes (δ2Hn-alkanes), is increasingly used for paleohydrological and paleoclimate reconstructions. However, it is challenging to disentangle past changes in the isotopic composition of precipitation and changes in evapotranspirative enrichment of leaf water, which are both recorded in leaf wax δ2H values. In order to overcome this limitation, Zech M. et al. (2013) proposed a coupled δ2Hn-alkanes–δ18Osugar biomarker approach. This coupled approach allows for calculating (i) biomarker-based "reconstructed" δ2Hδ18O values of leaf water (δ2Hδ18Oleaf water), (ii) biomarker-based reconstructed deuterium excess (d-excess) of leaf water, which mainly reflects evapotranspirative enrichment and which can be used to reconstruct relative air humidity (RH) and (iii) biomarker-based reconstructed δ2Hδ18Oprecipitation values. Here we present a climate transect validation study by coupling new results from δ2H analyses of n-alkanes and fatty acids in topsoils along a climate transect in Argentina with previously measured δ18O results obtained for plant-derived sugars. Accordingly, both the reconstructed RH and δ2Hδ18Oprecipitation values correlate highly significantly with actual RH and δ2Hδ18Oprecipitation values. We conclude that compared to single δ2Hn-alkane or δ18Osugar records, the proposed coupled δ2Hn-alkane–δ18Osugar biomarker approach will allow more robust δ2Hδ18Oprecipitation reconstructions in future paleoclimate research. Additionally, the proposed coupled δ2Hn-alkane–δ18Osugar biomarker approach allows for the establishment of a "paleohygrometer", more specifically, the reconstruction of mean summer daytime RH changes/history.
To make use of the isotope ratio of nonexchangeable hydrogen (δ(2)H(n (nonexchangeable))) of bulk soil organic matter (SOM), the mineral matrix (containing structural water of clay minerals) must be separated from SOM and samples need to be analyzed after H isotope equilibration. We present a novel technique for demineralization of soil samples with HF and dilute HCl and recovery of the SOM fraction solubilized in the HF demineralization solution via solid-phase extraction. Compared with existing techniques, organic C (C(org)) and organic N (N(org)) recovery of demineralized SOM concentrates was significantly increased (C(org) recovery using existing techniques vs new demineralization method: 58% vs 78%; N(org) recovery: 60% vs 78%). Chemicals used for the demineralization treatment did not affect δ(2)H(n) values as revealed by spiking with deuterated water. The new demineralization method minimized organic matter losses and thus artificial H isotope fractionation, opening up the opportunity to use δ(2)H(n) analyses of SOM as a new tool in paleoclimatology or geospatial forensics.
SUMMARYThe rainfall erosivity (R) and soil erodibility (K) factors of the Universal Soil Loss Equation (USLE) were determined on two sites in the Colombian Cauca Department over a five year period when rainfall was mostly lower than average. The results showed that the high erosion potential of the soils can be attributed more to high rain erosivity than soil erodibility. The R factor explained between 59 and 81% of the variation in soil loss recorded on continuously clean-tilled fallow plots. The erodibility of Inceptisols in the study region is classified as low. Values for soil erodibility (K) ranged from 0.012 to 0.015 (measured in SI units) in the fifth year of permanent bare fallowing. K factors were higher in the rainy than in the dry season. Soils, previously under grass vegetation, were very resistant to erosion in the first two years of bare fallowing. In the third year erodibility increased sharply and continued to increase steadily until the sixth year. K factors predicted by the USLE nomograph underestimated the empirically-determined erodibility of these highly aggregated clay soils.
Sediments of northern lakes sequester large amounts of organic carbon (OC), but direct evidence of the relative importance of their sources is lacking. We used stable isotope ratios of nonexchangeable hydrogen (d 2 H n ) in topsoil, algae, and surface sediments in order to measure the relative contribution of terrestrial OC in surface sediments of 14 mountainous arctic and lowland boreal lakes in Sweden. The terrestrial contribution to the sediment OC pool was on average 66% (range 46-80) and similar between arctic and boreal lakes. Proxies for the supply of terrestrial and algal OC explained trends in the relative contribution of terrestrial OC across lakes. However, the data suggest divergent predominant sources for terrestrial OC of sediments in Swedish lakes, with dissolved matter dominating in lowland boreal lakes and particulate OC in mountainous arctic lakes. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.This article was published online on 03 October 2017. An error was subsequently identified in the spelling of the Associate Editor name in the Acknowledgment section. This notice is included in the online version to indicate this has been corrected 18 October 2017.
Scientific Significance StatementLakes in boreal and arctic regions receive large amounts of organic carbon (OC) from their catchments, but also produce OC internally through primary production. The contribution of terrestrial vs. aquatic sources of OC to lake sediments in different bioclimatic settings is not known. This study provides evidence for generally large, but variable contributions of terrestrial OC to the sediments of lakes from boreal and arctic regions. Catchment properties and light explain trends in OC sources in sediments across lakes. However, differences between mountainous arctic and lowland boreal lakes suggest that particulate and dissolved OC are the predominant sources of sediment terrestrial OC in the arctic and boreal lakes, respectively.
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