Prussian blue (PB) represents a simple, economical, and eco-friendly system as cathode material for sodium-ion batteries (SIBs). However, structural problems usually worsen its experimental performance thus motivating the search for alternative synthetic strategies and the formation of composites that compensate these deficiencies. Herein, a straightforward approach for the preparation of PB/MoS 2 -based nanocomposites is presented. MoS 2 provides a 2D active support for the homogeneous nucleation of porous PB nanocrystals, which feature superior surface areas than those obtained by other methodologies, giving rise to a compact PB shell covering the full flake. The nanocomposite exhibits an excellent performance as cathode for SIBs with discharge capacity values up to 177 mA h g −1 and a specific capacitance of 354 F g −1 . These values are even larger for the intercalation of K + ions (up to 215 mA h g −1 , reaching a specific capacitance of 489 F g −1 ). Compared to similar composites, superior performance can be ascribed to a synergistic effect of the coordination compound with the 2D material.
Transition metal chalcogenophosphates of general formula MPX3 have attracted recent interest in the field of 2D materials due to the possibility of tuning their properties when reaching the 2D limit....
In this work we exploit the ability of spin-crossover molecules to switch between two spin states,
upon the application of external stimuli, to prepare smart molecular/2D heterostructures.
Through the chemical design of the hybrid interface, that involves a covalent grafting between
the two components, we obtain a hybrid heterostructure formed by spin-crossover nanoparticles
anchored on chemically functionalized monolayers of semiconducting MoS2. In the resulting
hybrid, the strain generated by the molecular system over the MoS2 layer, as a consequence of
a thermal or light-induced spin switching, results in a dramatic and reversible change of its
electrical and optical properties. This novel class of smart molecular/2D heterostructures could
open the way towards a novel generation of hybrid multifunctional materials and devices of
direct application in highly topical fields like electronics, spintronics or molecular sensing.
We present the covalent coating of chemically exfoliated molybdenum disulfide (MoS2) based on the polymerization of functional acryl molecules. The method relies on the efficient diazonium anchoring reaction to provoke the in situ radical polymerization and covalent adhesion of functional coatings. In particular, we successfully implement hydrophobicity on the exfoliated MoS2 in a direct, fast, and quantitative synthetic approach. The covalent functionalization is proved by multiple techniques including X-ray photoelectron spectroscopy and TGA-MS. This approach represents a simple and general protocol to reach dense and homogeneous functional coatings on 2D materials.
Functionalisation of two dimensional (2D) materials with stimuli-responsive molecules has been scarcely investigated. Here, MoS2 layers obtained by chemical exfoliation are covalently and non-covalently functionalised using two photoswitchable diarylethene derivatives...
The preparation of 2D stacked layers that combine flakes of different nature, gives rise to countless number of heterostructures where new band alignments, defined at the interfaces, control the electronic properties of the system. Among the large family of 2D/2D heterostructures, the one formed by the combination of the most common semiconducting transition metal dichalcogenides WS2/MoS2, has awaken great interest due to its photovoltaic and photoelectrochemical properties. Solution as well as dry physical methods have been developed to optimize the synthesis of these heterostructures. Here a suspension of negatively charged MoS2 flakes is mixed with a methanolic solution of a cationic W3S4-core cluster, giving rise to a homogeneous distribution of the clusters over the layers. In a second step, a calcination under N2 of this molecular/2D heterostructure leads to the formation of clean WS2/MoS2 heterostructures where the photoluminescence of both counterparts is quenched, proving an efficient interlayer coupling. Thus, this chemical method combines the advantages of a solution approach (simple, scalable and low-cost) with the good quality interfaces reached by using more complicated traditional physical methods.
In this work we exploit the ability of spin-crossover molecules to switch between two spin states,
upon the application of external stimuli, to prepare smart molecular/2D heterostructures.
Through the chemical design of the hybrid interface, that involves a covalent grafting between
the two components, we obtain a hybrid heterostructure formed by spin-crossover nanoparticles
anchored on chemically functionalized monolayers of semiconducting MoS2. In the resulting
hybrid, the strain generated by the molecular system over the MoS2 layer, as a consequence of
a thermal or light-induced spin switching, results in a dramatic and reversible change of its
electrical and optical properties. This novel class of smart molecular/2D heterostructures could
open the way towards a novel generation of hybrid multifunctional materials and devices of
direct application in highly topical fields like electronics, spintronics or molecular sensing.
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