10As the world's largest distributed store of freshwater, groundwater plays a central role in 11 sustaining ecosystems and enabling human adaptation to climate variability and change. 12The strategic importance of groundwater to global water and food security will intensify 13 under climate change as more frequent and intense climate extremes (droughts, floods) 14 increase variability in soil moisture and surface water. Here we critically review recent 15 research assessing climate impacts on groundwater through natural and human-induced 16 processes as well as groundwater-driven feedbacks on the climate system.

Boys' fighting was assessed at ages six, eight, and nine. The boys (N = 69) had been selected from the 30% most disruptive children in kindergartens from low socioeconomic neighborhoods. Twenty-three percent of these disruptive boys were rated as high fighters on three assessments ("stable high fighters"), and 28% were rated as high fighters on two of the three assessments ("variable high fighters"). Forty-two percent were rated as high fighters only one out of three assessments ("occasional high fighters") and 7% were never rated as high fighters. Only high fighting in two successive years significantly increased the risk of being rated a high fighter in a following year. At age 10, stable high fighters (high fighters at ages 6, 8, 9) were perceived by teachers, peers, mothers, and the boys themselves as more disruptive and more antisocial than occasional high fighters. These results show an impressive self-other agreement in boys who have adopted a physically aggressive life style from an early age. The three groups did not differ on individual family demographic characteristics, but stable high fighters had a higher mean on an index of family socioeconomic disadvantage. Results indicate that the aggression scales which include only a few physical aggression items and many disruptive items (oppositional behavior, rejection, hyperactivity, inattention, etc.) probably aggregate two kinds of disruptive boys, the high-frequency fighters at high risk for stable disruptive, physically aggressive, and antisocial behaviors, and the disruptive low-frequency fighters who are at a lower risk of stable disruptive behavior and at a lower risk of early antisocial behavior.

The Murray‐Darling Basin in southeast Australia is experiencing one of the most severe droughts observed recently in the world, driven by several years of rainfall deficits and record high temperatures. This paper provides new basin‐scale observations of the multiyear drought, integrated to a degree rarely achieved on such a large scale, to assess the response of water resources and the severity of the drought. A combination of Gravity Recovery and Climate Experiment (GRACE) data with in situ and modeled hydrological data shows the propagation of the water deficit through the hydrological cycle and the rise of different types of drought. Our observations show the rapid drying of soil moisture and surface water storages, which reached near‐stationary low levels only ∼2 years after the onset of the drought in 2001, with a loss of ∼80 and ∼12 km3 between January 2001 and January 2003, respectively. The multiyear drought has led to the almost complete drying of surface water resources which account for most of the water used for irrigation and domestic purposes. High correlation between observed groundwater variations and GRACE data substantiates the persistent reduction in groundwater storage, with groundwater levels still declining 6 years after the onset of the drought (groundwater loss of ∼104 km3 between 2001 and 2007). The hydrological drought continues even though the region returned to average annual rainfall during 2007.

Growth, tolerance and zinc and cadmium hyperaccumulation of Thlaspi caerulescens populations from three metal contaminated soils and three normal soils were compared under controlled conditions. Individuals of six populations were cultivated on five soils with increasing concentrations of zinc (50-25 000 µg g −" ) and cadmium (1-170 µg g −" ). There was no mortality of normal soil populations in the four metal-contaminated soils, but plant growth was reduced to half that of populations from metal-contaminated soils. However, in noncontaminated soil, the growth of individuals from normal soils was greater than that of individuals from metal-contaminated soils. Individuals from normal soils concentrated three times more zinc in the aboveground biomass than those from metal-contaminated soils, but the latter accumulated twice as much cadmium. We conclude that populations of T. caerulescens from both normal and metal-contaminated soils are interesting material for phytoextraction of zinc and cadmium, but to optimize the process of phytoextraction it is necessary to combine the extraction potentials of both type of populations.

The oxidation of Fe(II) in acid mine drainage (AMD) leads to the precipitation of Fe(III) compounds which may incorporate toxic elements, such as arsenic (As), within their structure or adsorb them at their surface, thus limiting their mobility. The present work provides evidence for spatial and seasonal variations of microbial activity that influence arsenite oxidation and As immobilization in the heavily contaminated AMD from the Carnoulès mine, Gard, France ([As III] = 80 to 280 mg x L(-1) in the acidic spring draining the waste-pile). In the first tens of meters of the AMD, the rapid oxidation of Fe(II) leads to the coprecipitation of large amounts of As with Fe(III) in bacterial mats. XRD, XANES, and SEM analyses of sediments and stromatolite samples revealed the unusual formation of As(III)-rich compounds, especially nanocrystalline tooeleite, Fe6(AsO3)4(SO4)(OH)4 x 4H2O, a rare ferric arsenite sulfate oxy-hydroxide mineral, together with XRD-amorphous mixed As(III)/As(V)-Fe(III) oxy-hydroxide compounds. In the wet season, the suspended sediments of the upstream zone essentially consist of tooeleite associated with am-As(III)-Fe(III) oxy-hydroxides, while am-As(V)-Fe(III) oxy-hydroxides, having As:Fe molar ratios as high as 0.6-0.8, dominate in the dry season. Comparing natural and bioassay samples revealed that the formation of As(III)-rich compounds in the wet season may be related to the metabolic activity of bacterial strains able to oxidize Fe(II) but not As(III). One of these strains, having an Acidithiobacillus ferrooxidans genotype, has been isolated from the Carnoulès AMD. In contrast, the formation of As(V)-rich compounds in the dry season can be related to both biotic and abiotic oxidation of As(III) to As(V). Some Thiomonas strains isolated from the Carnoulès AMD were shown to be able to catalyze the oxidation of As(III) to As(V) in solution. Therefore, they can promote the formation of mixed As(V)-Fe(III) oxy-hydroxides, provided enough Fe(II) oxidizes. These results yield a better understanding of natural processes at this site and may help in designing efficient As-removal processes.

The water table in southwestern Niger has been rising continuously for the past decades (4 m rise from 1963 to 2007), despite a ∼23% deficit in monsoonal rainfall from 1970 to 1998. This paradoxical phenomenon has been linked with a change in land use from natural savannah to millet crops that have expanded in area sixfold since 1950 and have caused soil crusting on slopes that has, in turn, enhanced Hortonian runoff. Runoff concentrates in closed ponds and then recharges the aquifer; therefore, higher runoff increases aquifer recharge. At the local scale (2 km2), a physically based, distributed hydrological model showed that land clearing increased runoff threefold, whereas the rainfall deficit decreased runoff by a factor of 2. At a larger scale (500 km2, 1950–1992 period), historical aerial photographs showed a 2.5‐fold increase in the density of gullies, in response to an 80% decrease in perennial vegetation. At the scale of the entire study area (5000 km2), analytical modeling of groundwater radioisotope data (3H and 14C) showed that the recharge rate prior to land clearing (1950s) was about 2 mm a−1; postclearing recharge, estimated from groundwater level fluctuations and constrained by subsurface geophysical surveys, was estimated to be 25 ± 7 mm a−1. This order of magnitude increase in groundwater fluxes has also impacted groundwater quality near ponds, as shown by a rising trend in groundwater nitrate concentrations of natural origin (75% of δ15N values in the range +4 to +8‰). In this well‐documented region of semiarid Africa, the indirect impacts of land use change on water quantity and quality are much greater than the direct influence of climate variability.

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