We attempt a systematic analysis of string-theoretic quintessence models as an alternative to metastable de Sitter vacua. It appears that, within the boundaries of what is known, largevolume type-IIB flux compactifications are preferred. Here the quintessence scalar is the ratio of certain 4-cycle volumes. It has already been noticed that the volume modulus, which must be stabilized, tends to remain too light. One may call this the "light volume problem". In addition, we identify an "F -term problem": The positive energy density of standard-model SUSY breaking is higher than the depth of all known negative contributions. We discuss what it would take to resolve these issues and comment on partially related challenges for axionic quintessence. In particular, large cancellations between positive and negative potential terms appear unavoidable in general. As a further challenge, one should then explain why a small de-tuning cannot be used to uplift into a deep slow-roll regime, violating de Sitter swampland conjectures.

It is widely believed that string theory easily allows for a QCD axion in the cosmologically favored mass range. The required small decay constant, fa ≪ MP, can be implemented by using a large compactification volume. This points to the Large Volume Scenario which in turn makes certain cosmological predictions: first, the closed string axion behaves similarly to a field-theoretic axion in the pre-inflationary scenario, i.e. the initial value can be tuned but one is constrained by isocurvature fluctuations. In addition, the volume represents a long-lived modulus that may lead to an early matter-dominated phase. Finally, the decay of the volume modulus to its own axion tends to overproduce dark radiation. In this paper we aim to carefully analyze the cosmology by studying models that not only allow for a QCD axion but also include inflation. Quite generally, limits on isocurvature fluctuations restrict us to relatively low-scale inflation, which in the present stringy context points to Kähler moduli inflation. As a novel feature we find that the lightest (volume) modulus couples strongly to the Higgs. It hence quickly decays to the SM, thus resolving the original dark radiation problem. This decay is much faster than that of the inflaton, implying that reheating is determined by the inflaton decay. The inflaton could potentially reintroduce a dark radiation problem since it decays to lighter moduli and their axions with equal rates. However, due its mixing with the QCD-saxion, the inflaton has also a direct decay rate to the SM, enhanced by the number of SM gauge bosons. This results in an amount of dark radiation that is consistent with present limits but potentially detectable in future measurements.

Sub-horizon perturbations in scalar-tensor theories have been shown to grow generically faster than in uncoupled models due to a positive, additive Yukawa force. In such cases, the amount of clustering becomes larger than in the standard cosmological model, exacerbating the observed tension in the σ8 parameter. Here we show instead that in some simple cases of conformally coupled dark energy one can obtain a transient regime of negative Yukawa force, without introducing ghosts or other instabilities.