Triggering rain on demand is an old dream of mankind, with a huge potential socio-economical benefit. To date, efforts have mainly focused on cloud-seeding using silver salt particles. We demonstrate that self-guided ionized filaments generated by ultrashort laser pulses are also able to induce water-cloud condensation in the free, sub-saturated atmosphere. Potential contributing mechanisms include photo-oxidative chemistry and electrostatic effects. As well as revealing the potential for influencing or triggering water precipitation, laser-induced water condensation provides a new tool for the remote sensing of nucleation processes in clouds

Carbon capture and storage is a viable greenhouse gas mitigation technology and the Sleipner CO2 sequestration site in the North Sea is an excellent example. Storage of CO2 at the Sleipner site requires monitoring over large areas, which can successfully be accomplished with time lapse seismic imaging. One of the main goals of CO2 storage monitoring is to be able to estimate the volume of the stored CO2 in the reservoir. This requires a parametrization of the subsurface as exact as possible. Here we use elastic 2D time‐domain full waveform inversion in a time lapse manner to obtain a P‐wave velocity constrain directly in the depth domain for a base line survey in 1994 and two post‐injection surveys in 1999 and 2006. By relating velocity change to free CO2 saturation, using a rock physics model, we find that at the considered location the aquifer may have been fully saturated in some places in 1999 and 2006.

The newly launched imaging spectrometer TROPOMI onboard the Sentinel-5 Precursor satellite provides atmospheric column measurements of sulfur dioxide (SO2) and other gases with a pixel resolution of 3.5 × 7 km2. This permits mapping emission plumes from a vast number of natural and anthropogenic emitters with unprecedented sensitivity, revealing sources which were previously undetectable from space. Novel analysis using back-trajectory modelling of satellite-based SO2 columns allows calculation of SO2 flux time series, which would be of great utility and scientific interest if applied globally. Volcanic SO2 emission time series reflect magma dynamics and are used for risk assessment and calculation of the global volcanic CO2 gas flux. TROPOMI data make this flux time series reconstruction approach possible with unprecedented spatiotemporal resolution, but these new data must be tested and validated against ground-based observations. Mt. Etna (Italy) emits SO2 with fluxes ranging typically between 500 and 5000 t/day, measured automatically by the largest network of scanning UV spectrometers in the world, providing the ideal test-bed for this validation. A comparison of three SO2 flux datasets, TROPOMI (one month), ground-network (one month), and ground-traverse (two days) shows acceptable to excellent agreement for most days. The result demonstrates that reliable, nearly real-time, high temporal resolution SO2 flux time series from TROPOMI measurements are possible for Etna and, by extension, other volcanic and anthropogenic sources globally. This suggests that global automated real-time measurements of large numbers of degassing volcanoes world-wide are now possible, revolutionizing the quantity and quality of magmatic degassing data available and insights into volcanic processes to the volcanological community.

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We performed simultaneous, multispectral CRDS measurements that for the first time use the Supercontinuum light source. We called this approach Supercontinuum Cavity Ring-Down Spectrography (SC CRDSpectrography) and successfully applied it to measuring the absorption spectrum of NO2 gas at a concentration of 2 ppm. The extrapolated sensitivity of our setup was much greater, about 5 ppb. The ppb sensitivity level is comparable to this obtainable with single wavelength dye-lasers based CRDS systems. It is, therefore, feasible to construct extremely broadband and sensitive CRDS devices basing on the SC CRDSpectrography scheme.

Motivated by the need for an extremely durable and portable instrument to quantify volcanic CO(2) we have produced a corresponding differential absorption lidar (DIAL). It was tested on a volcano (Vulcano, Italy), sensing a non-uniform volcanic CO(2) signal under turbulent atmospheric conditions. The measured CO(2) mixing ratio trend agrees qualitatively well but quantitatively poorly with a reference CO(2) measurement. The disagreement is not in line with the precision of the DIAL determined under conditions that largely exclude atmospheric effects. We show evidence that the disagreement is mainly due to atmospheric turbulence. We conclude that excluding noise associated with atmospheric turbulence, as commonly done in precision analysis of DIAL instruments, may largely underestimate the error of measured CO(2) concentrations in turbulent atmospheric conditions. Implications for volcanic CO(2) sensing with DIAL are outlined.

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