A series of carbon molecular sieves (CMSs) has been prepared, either as powders or monoliths, from petroleum pitch using potassium hydroxide as the activating agent. The CMS monoliths are prepared without the use of a binder based on the self-sintering ability of the mesophase pitch. Characterization results show that these CMSs combine a large apparent surface area (up to ca. 3100 m(2) g(-1)) together with a well-developed narrow microporosity (V(n) up to ca. 1.4 cm(3) g(-1)). The materials exhibit high adsorption capacities for CO(2) at 1 bar and 273 K (up to ca. 380 mg CO(2) g sorbent(-1)). To our knowledge, this is the best result obtained for CO(2) adsorption using carbon-based materials. Furthermore, although the CO(2) adsorption capacity for activated carbons has usually been considered lower than that of zeolites, the reported values exceed the total amount adsorbed on traditional 13X and 5A zeolites (ca. 230 mg and 180 mg CO(2) g sorbent(-1), respectively), under identical experimental conditions. Additionally, the narrow pore openings found in the CMS samples (ca. 0.4 nm) allows for the selective adsorption of CO(2) from molecules of similar dimensions (e.g., CH(4) and N(2)).
Natural methane hydrates are believed to be the largest source of hydrocarbons on Earth. These structures are formed in specific locations such as deep-sea sediments and the permafrost based on demanding conditions of high pressure and low temperature. Here we report that, by taking advantage of the confinement effects on nanopore space, synthetic methane hydrates grow under mild conditions (3.5 MPa and 2°C), with faster kinetics (within minutes) than nature, fully reversibly and with a nominal stoichiometry that mimics nature. The formation of the hydrate structures in nanospace and their similarity to natural hydrates is confirmed using inelastic neutron scattering experiments and synchrotron X-ray powder diffraction. These findings may be a step towards the application of a smart synthesis of methane hydrates in energy-demanding applications (for example, transportation).
Natural gas storage on porous materials (ANG) is a promising alternative to conventional on-board compressed (CNG) or liquefied natural gas (LNG). Until date, MOF materials have apparently been the only system published in the literature able to reach the new DOE value of 263 cm 3 (STP: 273.15K, 1 atm)/cm 3 ; however, this value was obtained by using the ideal single-crystal density to calculate the volumetric capacity. Here we prove experimentally and for the first time that properly designed activated carbon materials can really achieve the new DOE value but avoiding the additional drawback usually associated with MOF materials, i.e. the low mechanical stability under pressure (conforming) required for any practical application.
Although metal-organic framework (MOF) materials have been postulated as superior to any other sorbent for CO(2) adsorption at room temperature, here we prove that the appropriate selection of the raw material and the synthesis conditions allows the preparation of carbon molecular sieves (CMSs) with adsorption capacity, on a volumetric basis, highly exceeding those reported in the literature for MOFs. Furthermore, the excellent sorption properties of CMSs over the whole pressure range (up to 50 bar) are fully reversible after different adsorption/desorption cycles.
Activated carbons prepared from petroleum pitch and using KOH as activating agent exhibit an excellent behavior in CO 2 capture both at atmospheric (~168 mg CO 2 /g at 298 K) and high pressure (~1500 mg CO 2 /g at 298 K and 4.5 MPa). However, an exhaustive evaluation of the adsorption process shows that the optimum carbon structure, in terms of adsorption capacity, depends on the final application. Whereas narrow micropores (pores below 0.6 nm) govern the sorption behavior at 0.1 MPa, large micropores/small mesopores (pores below 2.0-3.0 nm) govern the sorption behavior at high pressure (4.5 MPa). Consequently, an optimum sorbent exhibiting a high working capacity for high pressure applications, e.g., pressure-swing adsorption units, will require a poorly-developed narrow microporous structure together with a highly-developed wide microporous and small mesoporous network. The appropriate design of 2 the preparation conditions gives rise to carbon materials with an extremely high delivery capacity ~1388 mg CO 2 /g between 4.5 MPa and 0.1 MPa. Consequently, this study provides guidelines for the design of carbon materials with an improved ability to remove carbon dioxide from the environment at atmospheric and high pressure.
The formation of methane hydrates on MOFs has been identified for the first time using inelastic neutron scattering and synchrotron X-ray powder diffraction.
Activated carbon binderless monoliths with high consistency and large porosity, synthesised from a mesophase pitch, are studied as electrodes for supercapacitors. The electrochemical cells prepared provided high capacitance values in sulphuric acid media (334 F g-1) and very low electrical resistivity, which results in a very efficient energy storage device (12 Wh Kg-1 maximum energy density and 12,000 W Kg-1 maximum power density). Long-term cycling experiments showed excellent stability with a reduction of the initial capacitance values of 19 % after performing 23,000 galvanostatic cycles at ∼300 mA g-1 .
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