Calculated molecular electrostatic potential difference (ΔMEP) of acceptor atoms in a multi component system will lead to different supramolecular architectures.
Co-crystallization technology was employed as a way of solving two problems hampering the usefulness of 4,4′,5,5′-tetranitro-2,2′biimidazole (TNBI) as a viable energetic material, namely hygroscopicity and corrosiveness (high acidity). Co-crystal screening was carried out with 15 co-formers containing nitrogen or oxygen as the primary hydrogen-bond acceptor site. Formation of co-crystals was confirmed by IR spectroscopy and DSC, and suitable co-crystals were then analysed via single-crystal X-ray diffraction. In each case, the formation of a co-crystal was driven by the formation of multiple N–H···N or N–H···O hydrogen bonds between TNBI and the co-former. The N-oxide based acceptors produce better energetic materials due to a more optimal oxygen balance. Hygroscopicity evaluations and corrosion tests revealed that the unavailability of N–H protons in the co-crystals of TNBI reduce hygroscopicity and suppress the chemical acidity of the free parent compound thereby making it substantially easier to handle, store, and transport.
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