The fluorescent N-doped carbon dots (N-CDs) obtained from C3N4 emit strong blue fluorescence, which is stable with different ionic strengths and time. The fluorescence intensity of N-CDs decreases with the temperature increasing, while it can recover to the initial one with the temperature decreasing. It is an accurate linear response of fluorescence intensity to temperature, which may be attributed to the synergistic effect of abundant oxygen-containing functional groups and hydrogen bonds. Further experiments also demonstrate that N-CDs can serve as effective in vitro and in vivo fluorescence-based nanothermometer.

Heteroatom (N, P, and B)-codoped nanocarbons (NPBC) with nanoporous morphology are fabricated via a facile one-step pyrolysis method and exhibit good electrocatalytic activity, durability, and selectivity for the oxygen reduction reaction (ORR) in alkaline media. The ORR activity of NPBC is better than single- (nitrogen-doped carbon (NC)) or dual-doped (nitrogen and phosphorus codoped carbon (NPC) or nitrogen and boron codoped carbon (NBC)) catalysts in terms of onset potential and current density. This synthetic approach is efficient and suitable for large-scale fabrication of metal-free carbon-based catalysts.

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Carbon dots (CDs) were synthesized by refluxing glucose, as efficient fluorescence probes, which show convenient and sensitive detection of norfloxacin (NOR) over a wide concentration range. It is worth noting that because of the hydrogen bond interactions between the CDs and NOR, the fluorescence intensity of CDs was remarkably enhanced in the presence of NOR, which indicates that CDs are capable of rapid, stable and sensitive determination of NOR. Compared with high-performance liquid chromatography, the fluorescence enhancement method is considerably simpler and faster, and will pave a new way for the determination of NOR.

Overlay multicast constructs a multicast delivery tree among end hosts. Unlike traditional IP multicast, the non-leaf nodes in the tree are normal end hosts, which are potentially more susceptible to failures than routers and may leave the multicast group voluntarily. In these cases, all downstream nodes are affected. Thus, an important problem for making overlay multicast more dependable is how to recover from node departures in order to minimize the disruption of service to those affected nodes. In this paper, we propose a proactive tree recovery mechanism to make the overlay multicast resilient to these failures and unexpected events. Rather than letting downstream nodes try to find a new parent after a node departure, each non-leaf node precalculates a parent-to-be for each of its children. When this non-leaf node is gone, all its children can find their respective new parents immediately. The salient feature of the approach is that rescue plans for multiple non-leaf nodes can work together for their respective children when they fail or leave at the same time. Extensive simulations demonstrate that our proactive approach can recover from node departures much faster than reactive methods, while the quality of trees restored and the cost of recovery are reasonable.

Efficient, stable, and low‐cost electrocatalysts for the oxygen evolution and reduction reactions (OER and ORR) are essential components of energy conversion. Although much progress has been achieved in the development of platinum‐based electrocatalysts for ORR and iridium‐based electrocatalysts for OER, they are still not yet viable for large‐scale commercialization because of the high cost and scanty supply of the noble metals. Here, it is demonstrated that carbon nanodots surface‐modified with either phosphorus or amidogen can respectively achieve electrocatalytic activity approaching that of the benchmark Pt/C and IrO2 /C catalysts for ORR and OER. Furthermore, phosphorus (amidogen)‐modified carbon nanodots with attached Au nanoparticles exhibit superior ORR (OER) activity better than commercial Pt/C (IrO2/C) catalysts as well as excellent electrochemical stability under visible light.

X-ray detection is widely used in medical imaging, safety inspection, scientific research, and so on, in which the Cs 3 Bi 2 I 9 perovskite single crystal (SC) material has attracted increasing attentions for its excellent intrinsic properties (high X-ray absorption coefficient, low toxicity, high resistivity, etc.). However, existing methods for this SC growth enable low quality and high preparation cost, thus resulted in the defects of limit sensitivity, detectable dose rate, and large-scale application of the Cs 3 Bi 2 I 9 -based device. In this work, high-quality Cs 3 Bi 2 I 9 perovskite SCs were successfully grown by the novel top-seed solution (TSS) method, which contains the advantages of constant growth rate, simple system and high yield. Due to the high quality of TSS-based Cs 3 Bi 2 I 9 SC, the X-ray detector exhibited high sensitivity of 4382 μC•Gy air −1 cm −2 at 20 V mm −1 bias. Under 7.93 nGy air s −1 X-ray irradiation, the signal-to-noise ratio reached 27.9. This work presents a new strategy for the low-cost growth of high-quality Cs 3 Bi 2 I 9 perovskite SC.

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