This brief review discusses methods to locate and characterize first order phase transitions, paying particular attention to finite size effects. In the first part, the order parameter probability distribution and its fourth-order cumulant is discussed for thermally driven first-order transitions (the 3-state Potts model in d=3 dimensions is treated as an example). First-order transitions are characterized by a minimum of the cumulant, which gets very deep for large enough systems. In the second part, we discuss how to locate first order phase boundaries ending in a critical point in a large parameter space. As an example, the study of the unmixing transition of asymmetric polymer mixtures by a combination of histogram techniques and finite size scaling is described. As a final problem, we discuss the shift of the gas-liquid condensation in thin-film geometry confined between two parallel plates due to boundary fields (“capillary condensation”). Being interested in temperatures far below bulk criticality (e. g. near the wetting transition), special thermodynamic integration techniques are the method of choice, rather than the use of finite sizes scaling to map out the (asymmetric) phase diagram.
An arrangement of pseudocircles is a collection of simple closed curves on the sphere or in the plane such that any two of the curves are either disjoint or intersect in exactly two crossing points. We call an arrangement intersecting if every pair of pseudocircles intersects twice. An arrangement is circularizable if there is a combinatorially equivalent arrangement of circles.In this paper we present the results of the first thorough study of circularizability. We show that there are exactly four non-circularizable arrangements of 5 pseudocircles (one of them was known before). In the set of 2131 digon-free intersecting arrangements of 6 pseudocircles we identify the three non-circularizable examples. We also show non-circularizability of 8 additional arrangements of 6 pseudocircles which have a group of symmetries of size at least 4.Most of our non-circularizability proofs depend on incidence theorems like Miquel's. In other cases we contradict circularizability by considering a continuous deformation where the circles of an assumed circle representation grow or shrink in a controlled way.The claims that we have all non-circularizable arrangements with the given properties are based on a program that generated all arrangements up to a certain size. Given the complete lists of arrangements, we used heuristics to find circle representations. Examples where the heuristics failed were examined by hand.
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