The crystal structure of ionic nanocrystals (NCs) is usually controlled through reaction temperature, according to their phase diagram. We show that when ionic NCs with different shapes, but identical crystal structures, were subjected to anion exchange reactions under ambient conditions, pseudomorphic products with different crystal systems were obtained. The shape-dependent anionic framework (surface anion sublattice and stacking pattern) of Cu2O NCs determined the crystal system of anion-exchanged products of CuxS nanocages. This method enabled us to convert a body-centered cubic lattice into either a face-centered cubic or a hexagonally close-packed lattice to form crystallographically unusual, multiply twinned structures. Subsequent cation exchange reactions produced CdS nanocages while preserving the multiply-twinned structures. A high-temperature stable phase such as wurtzite ZnS was also obtained with this method at ambient conditions.

No abstract

This paper is concerned with the uniqueness, existence, comparison principle and long-time behavior of solutions to the initial-boundary value problem for a unidirectional diffusion equation. The unidirectional evolution often appears in Damage Mechanics due to the strong irreversibility of crack propagation or damage evolution. The existence of solutions is proved in an L 2 -framework by introducing a peculiar discretization of the unidirectional diffusion equation by means of variational inequities of obstacle type and by developing a regularity theory for such variational inequalities. The novel discretization argument will be also applied to prove the comparison principle as well as to investigate the long-time behavior of solutions.

Recently, wind energy conversion system using a Doubly-Fed Synchronous Generator (DFSG) has attracted an interest. This system can control rapidly real and reactive power output independently by secondary AC excitation. Furthermore, since wind turbine can be operated in variable speed, fluctuations of the output due to changing wind speed in short period can be reduced. This paper proposes a new control method for this system to enhance the transient stability of neighboring induction generators in the same wind farm.

A new numerical scheme of the boundary tracking method for moving boundary problems is proposed. A key point of the scheme is to avoid concentration of tracking points on the moving boundary, and a convergence theorem is proved for the curve shortening problem. Some numerical examples for the curve shortening problem and the Hele-Shaw problem by the proposed scheme are shown.

Infrared-light-induced carrier transfer is a key technology for ‘invisible’ optical devices for information communication systems and energy devices. However, clear and colourless photo-induced carrier transfer has not yet been demonstrated in the field of photochemistry, to the best of our knowledge. Here, we resolve this problem by employing short-wavelength-infrared (1400–4000 nm) localized surface plasmon resonance-induced electron injection from indium tin oxide nanocrystals to transparent metal oxides. The time-resolved infrared measurements visualize the dynamics of the carrier in this invisible system. Selective excitation of localized surface plasmon resonances causes hot electron injection with high efficiency (33%) and long-lived charge separation (~ 2–200 μs). We anticipate our study not only provides a breakthrough for plasmonic carrier transfer systems but may also stimulate the invention of state-of-the-art invisible optical devices.

It is often observed that thermal stress enhances crack propagation in materials, and, conversely, crack propagation can contribute to temperature shifts in materials. In this study, we first consider the thermoelasticity model proposed by M. A. Biot and study its energy dissipation property. The Biot thermoelasticity model takes into account the following effects. Thermal expansion and contraction are caused by temperature changes, and, conversely, temperatures decrease in expanding areas but increase in contracting areas. In addition, we examine its thermomechanical properties through several numerical examples and observe that the stress near a singular point is enhanced by the thermoelastic effect. In the second part, we propose two crack propagation models under thermal stress by coupling a phase field model for crack propagation and the Biot thermoelasticity model and show their variational structures. In our numerical experiments, we investigate how thermal coupling affects the crack speed and shape. In particular, we observe that the lowest temperature appears near the crack tip, and the crack propagation is accelerated by the enhanced thermal stress.

Nonlinear magnetization dynamics excited by spin-transfer effect with feedback current is studied both numerically and analytically. The numerical simulation of the Landau-Lifshitz-Gilbert equation indicates the positive Lyapunov exponent for a certain range of the feedback rate, which identifies the existence of chaos in a nanostructured ferromagnet. Transient behavior from chaotic to steady oscillation is also observed in another range of the feedback parameter. An analytical theory is also developed, which indicates the appearance of multiple attractors in a phase space due to the feedback current. An instantaneous imbalance between the spin-transfer torque and damping torque causes a transition between the attractors, and results in the complex dynamics.PACS numbers: