The supramolecular chemistry and crystal structures of five bis(imidazolium 2,6-pyridinedicarboxylate)M(II) trihydrate complexes, where M ) Mn 2+ , Co 2+ , Ni 2+ , Cu 2+ , or Zn 2+ (1-5, respectively), are reported. These complexes serve as supramolecular building blocks that self-assemble when crystallized to generate a single, well-defined, predictable structure in the solid state. 2,6-Pyridinedicarboxylate anions and imidazolium cations form strong ionic hydrogen bonds that dominate crystal packing in compounds 1-5 by forming twodimensional networks, or layers of molecules. This layer motif serves as a platform with which to control and predict molecular packing by design for engineering the structures of crystals. Moreover, compounds 1-5 create a robust organic host lattice that accommodates five different transition metals without significantly altering molecular packing. Growth of crystals from solutions that contain two or more different metal complexes produces mixed crystals in which mixtures of the different metal complexes are incorporated in the same relative molar ratio present in solution. Epitaxial growth of crystals from one metal complex on the surface of a seed crystal that contains a second metal complex generates composite crystals in which the different metal complexes are segregated into different regions of the crystals. Compounds 1-5 form crystalline solids that represent a new class of modular materials in which the organic ligands serve as a structural component that defines a single packing arrangement that persists over a range of structures, and in which the metal serves as an interchangeable component with which to vary the physical properties of the material.
The supramolecular chemistry and crystal structures of salts of imidazole with one monocarboxylic acid (1), nine different dicarboxylic acids (2−10), and one tetracarboxylic acid (11) are reported. Salts 2−11 serve as building blocks that self-assemble via ionic O−H···O and N−H···O hydrogen bonds when crystallized. These strong hydrogen bonds generate two types of chains that intersect at the anions and form polar hydrogen-bonded layers with four different motifs. These layers serve as scaffolds with which to control molecular packing in two dimensions for engineering the structures of crystals. All imidazolium cations function as multidentate proton donors by forming two or three C−H···O hydrogen bonds in addition to two N−H···O hydrogen bonds. Strong O−H···O and N−H···O hydrogen bonds define structure and connectivity within layers, while weaker C−H···O hydrogen bonds dominate interactions between layers in these salts.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.