The objective of this work was to investigate the mechanism of the inhibition of aggregation of petroleum asphaltenes using new ionic liquids (IL). The ionic liquids conjugate a good solubility in nonpolar environment with strong electron donor-acceptor properties. In this study, 1-propyl boronic acid-3-alkylimidazolium bromides and 1-propenyl-3-alkylimidazolium bromides were tested. A lateral chain containing either the boronic acid or the propenyl moiety was substituted for the classical 1-methyl-3-alkylimidazolium bromide. The boronic acid is a weak acid but a very efficient Lewis acid. It was demonstrated that the presence of the boronic acid moiety enhances interactions between asphaltenes and ionic liquids and limits considerably asphaltene aggregation. The length of the side alkyl chain of the ionic liquid is an important parameter also. The minimum length of eight carbons was necessary to obtain sterical stabilization of IL-asphaltene complexes.
Activity coefficients at infinite dilution γ∞ of 28 organic compounds in eight room-temperature ionic liquids of
the family of 1-propyl boronic acid-3-alkylimidazolium bromide and 1-propenyl-3-alkylimidazolium bromide
(with alkyl = methyl, octyl, decyl, or dodecyl) were determined at 323.15 K using inverse gas chromatography.
Using all the available γ∞ data, the selectivities at infinite dilution
were determined. Indeed, such values are
extremely useful for the design and the optimization of separation processes.
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