We study the distribution of multivalent counterions next to a dielectric slab, bearing a quenched, random distribution of charges on one of its solution interfaces, with a given mean and variance, both in the absence and in the presence of a bathing monovalent salt solution. We use the previously derived approach based on the dressed multivalent-ion theory that combines aspects of the strong and weak coupling of multivalent and monovalent ions in a single framework. The presence of quenched charge disorder on the charged surface of the dielectric slab is shown to substantially increase the density of multivalent counterions in its vicinity. In the counterion-only model (with no monovalent salt ions), the surface disorder generates an additional logarithmic attraction potential and thus an algebraically singular counterion density profile at the surface. This behavior persists also in the presence of a monovalent salt bath and results in significant violation of the contact-value theorem, reflecting the anti-fragility effects of the disorder that drive the system towards a more "ordered" state. In the presence of an interfacial dielectric discontinuity, depleting the counterion layer at the surface, the charge disorder still generates a much enhanced counterion density further away from the surface. Likewise, the charge inversion and/or overcharging of the surface occur more strongly and at smaller bulk concentrations of multivalent counterions when the surface carries quenched charge disorder. Overall, the presence of quenched surface charge disorder leads to sizable effects in the distribution of multivalent counterions in a wide range of realistic parameters and typically within a distance of a few nanometers from the charged surface.

In this article we study a fully relativistic model of a two dimensional hard-disk gas. This model avoids the general problems associated with relativistic particle collisions and is therefore an ideal system to study relativistic effects in statistical thermodynamics. We study this model using molecular-dynamics simulation, concentrating on the velocity distribution functions. We obtain results for x and y components of velocity in the rest frame (Γ) as well as the moving frame (Γ ′ ). Our results confirm that Jüttner distribution is the correct generalization of Maxwell-Boltzmann distribution. We obtain the same "temperature" parameter β for both frames consistent with a recent study of a limited one-dimensional model. We also address the controversial topic of temperature transformation. We show that while local thermal equilibrium holds in the moving frame, relying on statistical methods such as distribution functions or equipartition theorem are ultimately inconclusive in deciding on a correct temperature transformation law (if any).

We study the effective interaction mediated by strongly coupled Coulomb fluids between dielectric surfaces carrying quenched, random monopolar charges with equal mean and variance, both when the Coulomb fluid consists only of mobile multivalent counterions and when it consists of an asymmetric ionic mixture containing multivalent and monovalent (salt) ions in equilibrium with an aqueous bulk reservoir. We analyze the consequences that follow from the interplay between surface charge disorder, dielectric and salt image effects, and the strong electrostatic coupling that results from multivalent counterions on the distribution of these ions and the effective interaction pressure they mediate between the surfaces. In a dielectrically homogeneous system, we show that the multivalent counterions are attracted towards the surfaces with a singular, disorder-induced potential that diverges logarithmically on approach to the surfaces, creating a singular but integrable counterion density profile that exhibits an algebraic divergence at the surfaces with an exponent that depends on the surface charge (disorder) variance. This effect drives the system towards a state of lower thermal 'disorder', one that can be described by a renormalized temperature, exhibiting thus a remarkable antifragility. In the presence of an interfacial dielectric discontinuity, the singular behavior of counterion density at the surfaces is removed but multivalent counterions are still accumulated much more strongly close to randomly charged surfaces as compared with uniformly charged ones. The interaction pressure acting on the surfaces displays in general a highly non-monotonic behavior as a function of the inter-surface separation with a prominent regime of attraction at small to intermediate separations. This attraction is caused directly by the combined effects from charge disorder and strong coupling electrostatics of multivalent counterions, which dominate the surface-surface repulsion due to the (equal) mean charges on the two surfaces and the osmotic pressure of monovalent ions residing between them. These effects can be quite significant even with a small degree of surface charge disorder relative to the mean surface charge. The strong coupling, disorder-induced attraction is typically much stronger than the van der Waals interaction between the surfaces, especially within a range of several nanometers for the inter-surface separation, where such effects are predicted to be most pronounced.

In this paper we consider the effect of different time parameterizations on the stationary velocity distribution function for a relativistic gas. We clarify the distinction between two such distributions, namely the Jüttner and the modified Jüttner distributions. Using a recently proposed model of a relativistic gas, we show that the obtained results for the proper-time averaging does not lead to modified Jüttner distribution (as recently conjectured), but introduces only a Lorentz factor γ to the well-known Jüttner function which results from observer-time averaging. We obtain results for rest frame as well as moving frame in order to support our claim.

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We investigate the effective interaction between two randomly charged but otherwise net-neutral, planar dielectric slabs immersed in an asymmetric Coulomb fluid containing a mixture of mobile monovalent and multivalent ions. The presence of charge disorder on the apposed bounding surfaces of the slabs leads to substantial qualitative changes in the way they interact, as compared with the standard picture provided by the van der Waals and image-induced, ion-depletion interactions. While, the latter predict purely attractive interactions between strictly neutral slabs, we show that the combined effects from surface charge disorder, image depletion, Debye (or salt) screening, and also, in particular, their coupling with multivalent ions, give rise to a more diverse behavior for the effective interaction between net-neutral slabs at nano-scale separations. Disorder effects show large variation depending on the properly quantified strength of disorder, leading either to non-monotonic effective interaction with both repulsive and attractive branches when the surface charges are weakly disordered (small disorder variance) or to a dominating attractive interaction that is larger both in its range and magnitude than what is predicted from the van der Waals and image-induced, ion-depletion interactions, when the surfaces are strongly disordered (large disorder variance).

Relativistic transport phenomena are important from both theoretical and practical point of view. Accordingly, hydrodynamics of relativistic gas has been extensively studied theoretically. Here, we introduce a three-dimensional canonical model of hard-sphere relativistic gas which allows us to impose appropriate temperature gradient along a given direction maintaining the system in a non-equilibrium steady state. We use such a numerical laboratory to study the appropriateness of the so-called first order (Chapman-Enskog) relativistic hydrodynamics by calculating various transport coefficients. Our numerical results are consistent with predictions of such a theory for a wide range of temperatures. Our results are somewhat surprising since such linear theories are not consistent with the fundamental assumption of the special theory of relativity ($v\leq c$). We therefore seek to explain such results by studying the appropriateness of diffusive transport in the relativistic gas, comparing our results with that of a classical gas. We find that the relativistic correction (constraint) in the hydrodynamic limit amounts to small negligible corrections, thus indicating the validity of the linear approximation in near equilibrium transport phenomena.Comment: 8 pages, 5 figures. To appear in Physical Review

Recently, a morphological transition in the velocity distribution of a relativistic gas has been pointed out which shows hallmarks of a critical phenomenon. Here, we provide a general framework which allows for a thermodynamic approach to such a critical phenomenon. We therefore construct a thermodynamic potential which upon expansion leads to Landau-like (mean-field) theory of phase transition. We are therefore able to calculate critical exponents and explain the spontaneous emergence of order parameter as a result of relativistic constraints. Numerical solutions which confirm our thermodynamic approach are also provided. Our approach provides a general understanding of such a transition as well as leading to some new results. Finally, we briefly discuss some possible physical consequences of our results as well as considering the case of quantum relativistic gases.Comment: 5 pages, 5 figures. To appear in Physica