Thanks to the continuous development of light-curing resin composites it is now possible to print permanent single-tooth restorations. The purpose of this study was to compare resin composites for milling -Gandio Blocks(GR), Brilliant Crios(CR) and Enamic(EN) with resin composite for 3D printing—VarseoSmileCrown plus(VSC). Three-point bending was used to measure flexural strength (σf) and flexural modulus (Ef). The microhardness was measured using a Vickers method, while fractographic, microstructural, texture and fractal dimension (FD) analyses were performed using SEM, optical microscope and picture analysis methods. The values of σf ranged from 118.96 (±2.81) MPa for EN to 186.02 (±10.49) MPa for GR, and the values of Ef ranged from 4.37 (±0.8) GPa for VSC to 28.55 (±0.34) GPa for EN. HV01 ranged from 25.8 (±0.7) for VSC to 273.42 (±27.11) for EN. The filler content ranged from 19–24 vol. % for VSC to 70–80 vol. % for GR and EN. The observed fractures are typical for brittle materials. The correlation between FD of materials microstructure and Ef was observed. σf of the printed resin depends on layers orientation and is significantly lower than σf of GR and CR. Ef of the printed material is significantly lower than Ef of blocks for milling.
This article presents a study of corrosion resistance of tin and tin-based composite (Sn + Al 2 O 3 and Sn + SiC) coatings deposited onto aluminium alloy substrates using the low-pressure cold spraying method. The samples were subjected to three different corrosion tests at a room temperature: (i) Kesternich test, (ii) a cyclic salt spray test and (iii) anodic polarisation test. The selected tests allowed extreme environment simulation typical for wide range of urban, industrial and marine service conditions. Evaluation of corrosion was carried out by analysing changes on the coating surface as well as in the microstructure. Additionally, the physicochemical tests were carried out using X-ray diffraction. XRD analysis clearly showed that abhurite Sn 21 O 6 Cl 16 (OH) 14 is the main corrosion product established after the polarisation measurements. Despite extreme corrosive conditions used in experiments all tin coatings showed minor corrosion changes which implies that abhurite serves as a buffer between the metal and the oxidising natural environment.
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