Global warming affected by human activities causes changes in the regime of rivers. Rivers are one of the most vital sources that supply fresh water. Therefore, management, planning, and proper use of rivers will be crucial for future climate change conditions. This study investigated the monitoring of hydrological drought in a future period to examine the impact of climate change on the discharging flow of the Zard River basin in Iran. Zard River is an important supplier of fresh and agricultural water in a vast area of Khuzestan province in Iran. A continuous rainfall-runoff model based on Soil Moisture Accounting (SMA) algorithm was applied to simulate the discharge flow under 10 scenarios (obtained from LARS-WG.6 software) of future climate change. Then, the Stream-flow Drought Index (SDI) and the Standard Precipitation Index (SPI) were calculated for each climate change scenario for the future period (2041–2060). The results of the meteorological drought assessment showed that near normal and moderate droughts had higher proportions among other drought conditions. Moreover, the hydrological drought assessment showed the occurrence of two new droughts (severe and extreme) conditions for the future period (2041–2060) that has never happened in the past (1997–2016).
Background: Chloroform, as a hazardous chemical, can contaminate water resources via the reaction of chlorine as an antiseptic chemical with humic acids resulted from agricultural activities. In humans, chloroform may cause dizziness, heart disorders, and disorders of the nervous system. Hence, its removal is of crucial importance. Objectives: The current study aimed to propose cheap and efficient adsorbents to remove chloroform from water. Methods: Four different nanomaterials (ZnO, ZnO/graphene oxide (ZnO/GO), ZnO/GO/Zeolite, and GO/Zeolite nanocomposites) were prepared and characterized with X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM) images. Textural properties of the nano- adsorbents were evaluated using Brunauer Emmet Teller (BET) and Barrett-Joyner-Halenda (BJH) techniques. Different isotherms and kinetic models were studied. The effect of pH on the removal efficiency of the nano-adsorbents was tested. Regenerability of the nano-adsorbents towards the removal of the chloroform was also evaluated. Results: XRD patterns and FESEM images of the nanocomposites confirmed lattice structures and nanoscale particle size of the prepared nanocomposites. According to the BET and BJH models, all samples had mesoporous structures. The BJH cumulative surface area of pores of ZnO, ZnO/GO, ZnO/GO/Zeolite, and GO/Zeolite nanocomposites were 8.5, 26.4, 17.2, and 20.8 m2/g, respectively. The best removal speed and efficiency were obtained according to the different isotherm and kinetic models for the removal of chloroform ZnO/GO nanocomposites. All adsorbents revealed characteristic adsorption in the pH range of 7 to 8. Conclusion: The ZnO/GO, a cheap and efficient nanocomposite, showed the best performance to remove chloroform from water samples due to its superior textural property. Hence, it can be used to remove chloroform from water for up to 5 cycles.
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