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The Santa Barbara Amorphous (SBA-15), with a large surface area covered with abundant Si-OH active groups on the walls of its pores, can be modified with various organic compounds to build organic-inorganic hybrid materials, which can be used as a catalyst in organic reactions, drug delivery systems, nano sorbent due to its high capacity for removing heavy metals in wastewater and as chemosensors for ions. Tunable and straight channels of SBA-15 facilitate the entrance and diffusion of ions through the channels. This paper presents a review of the past five years of literature covering the application of SBA-15 as ions chemosensor in the liquid and gaseous media.
2,2-bis(1H-indol-3-yl)acenaphthylene-1(2H)-ones were synthesised by the reaction of acenaphthenequinone and 2 equivalents of indole using Fe3O4@SiO2@Si-Pr-NH-CH2CH2NH2 as the basic magnetic nanocatalyst, assembled under greener and sustainable conditions in high purity and yields. Furthermore, the photoluminescence properties of 2,2-bis(2-methyl-1H-indol-3-yl)acenaphthylene-1(2H)-one were exploited for the sensing of copper ions in the mixed solvent systems comprising H2O and CH3CN in excitation wavelength at 410 nm with a detection limit of 9.5 ∙ 10–6 M.
Barbituric acid is a pyrimidine heterocyclic organic compound, which is pharmacologically active. It is important to build structures containing various medicinal activities. This compound attracts the scientific research community in organic synthesis. It can be used in the synthesis of polyheterocyclic, natural, medicinal compounds, and organic sensors. Herein, the utilization of barbituric or thiobarbituric acid in multicomponent reactions is reported from 2016-2021 in this manuscript.
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