ABSTRACT:Cotton and cotton/polyester fabrics were treated against microbial attack by applying a formulation based essentially on ZnO under high-energy radiation and thermal curing. To achieve the homogeneity and the reactivity of the treating formulation, a binder (Impron MTP) and a dispersing agent (Setamol WS) were used with ZnO. The antimicrobial property of the fabrics was evaluated, in terms of mechanical properties, by a soil burial test. Moreover, the effect of antimicrobial finishing on the dyeing properties in terms of color strength was investigated. It was found that the best composition that affords the best antimicrobial protection to cotton fabrics contains 2% ZnO, 2% binder, and 1% dispersing agents. For the cotton/polyester blend, the best results were achieved at the same conditions except the ZnO was 1%. It was found that the treatment under the effect of electron-beam irradiation is better than that of gamma irradiation and thermal curing. The results showed that when the finishing process was carried out before dyeing with a reactive dye, it affects the color strength rather than performing the finishing after the dyeing process.

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Radiation‐induced grafting of binary mixtures of acrylonitrile (AN)/styrene (S) and acrylamide (AAm)/styrene (S) onto polyester fabric (PET) has been investigated. Synergism during radiation grafting was investigated by determining the graft yield fraction for each monomer in the final graft copolymer. Moreover, by knowing the mole fraction of each monomer in the grafting solution, the reactivity ratio of the individual monomers in the comonomer mixture during graft copolymerization could be determined: in the case of AN/S comonomer mixture, the calculated reactivity ratios for AN and S are 0.04 and 0.05, respectively; the calculated reactivity ratios of AAm and S in their comonomer mixture are 1.82 and 0.41, respectively. © 2001 Society of Chemical Industry

Radiation graft copolymerization of individual and comonomer mixtures of vinyl monomers onto polyester and cotton/polyester fabrics by the mutual method has been investigated. The effect of factors that may affect the grafting yield, such as solvent composition, comonomer mixture composition and radiation dose, have been examined. Suitable conditions that gives the highest graft yield without altering the original properties of the substrates are reported briefly. An attempt was made to determine the graft yield fraction from each monomer in the final graft copolymer in the case of grafting comonomer mixtures by using elemental analysis of nitrogen. Moreover, the results of elemental analysis were used to determine the reactivity ratios of the vinyl monomers. Some selective properties of the graft copolymers of polyester and cotton/polyester with the individual and comonomer mixtures have been investigated. The studied properties are the dye affinity for various dyestuffs and the mechanical properties in terms of tensile strength, elongation at break and Young's modulus. In general and regardless of the system used, grafting improves the dyeability of polyester and cotton/polyester with basic, vat, acid and disperse dyes. Also, it was found that improvement in dyeing and mechanical properties depends essentially on the composition of the graft copolymer and not on the composition of the feed comonomer solution or the total graft yield. © 1999 Society of Chemical Industry

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Cotton and cotton/polyester fabrics were treated with a proposed antimicrobial formulation based on zinc oxide (ZnO), Impron MTP (binder), and Setamol WS (dispersing agent) under the effect of ␥ irradiation. The effect of this treatment on the growth of certain bacteria (Bacillus subtilis) and fungi (Aspergillus niger) was studied. In general, it has been confirmed that ZnO ratio is an inhibitory factor on the growth of both microbes. As a result of treatment of cotton fabrics, as an example, the B. subtilis counts were decreased by 4 log cycles whereas the A. niger count was decreased by 2 log cycles. This finding was illustrated by observing the surface microstructure of the fabrics after they had been buried in a moist soil for two weeks. The deterioration in the weaving structure of the nontreated was so strong that it could not distinguish the strings forming the fabric. On the basis of microbial detection, it was found that the treatment with ZnO formulation causes a net reduction in the bacterial cells amounts to 78 and 62% in the case of treated cotton and cotton/polyester fabrics while the net reduction in the fungi was calculated to be 80.7 and 32%, respectively. However, it was found that the treatment with ZnO formulation caused a reduction in the thermal stability of the fabrics as indicated by thermogravimetric analysis.