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Although plenty of functional nanomaterials are widely applied in science and technology, cost-efficient, controlled and reproducible fabrication of metallic nanostructures is a considerable challenge. Automated electrorefining by scanning electrochemical microscopy (SECM) provides an effective approach to circumvent some drawbacks of traditional homogeneous syntheses of nanoparticles, providing precise control over the amount, time and place of reactant delivery. The precursor is just a raw metal, which is the most economically viable source. This approach ensures reproducibility and the opportunity for fabrication of micropatterns, which can be rapidly analyzed by scanning probe techniques. Here, a cost-effective methodology for the preparation of naked (ligand-free) metallic nanostructures, from polycrystalline gold using a moving microelectrode, is presented. Automated micropatterning of bare gold on indium tin oxide (ITO) demonstrates the versatility of this method to tune the size and shape of the nanostructures. The morphology of the obtained materials and thus their catalytic and plasmonic properties can be tuned using the electrorefining parameters. Programmable fabrication of sample microarrays by microprinting followed by comparative SECM studies or spectroscopic analysis allows quick optimization and characterization for specific purposes. Electrocatalytic oxygen reduction in alkaline media and surface-enhanced Raman spectroscopy (SERS) of single porphycene molecules are presented as model examples.

The role of butylbenzene carbenium ions in the acid catalyzed cracking of polystyrene. Transformation of n-butylbenzene, sec-butylbenzene, iso-butylbenzene, tert-butylbenzene, 4-phenyl-1-butene, n-propylbenzene and n-hexylbenzene over silicaalumina and alumina acid catalysts . It is proposed that phenylbutenyl carbenium ion obtained due to dealkylation reaction converts into coke by the successive elimination of H ? and Hions, which in turn take part in hydrogen transfer reactions resulting in the hydrogenation of styrene dimers to diphenylbutane. The dealkylation of this compound leads to active c-butylbenzene carbenium ion which is a key intermediate for the formation of indane and naphthalene derivatives.