A theoretical simulator of immiscible displacement of a non-wetting fluid by a wetting one in a random porous medium is developed. The porous medium is modelled as a network of randomly sized unit cells of the constricted-tube type. Under creeping-flow conditions the problem is reduced to a system of linear equations, the solution of which gives the instantaneous pressures at the nodes and the corresponding flowrates through the unit cells. The pattern and rate of the displacement are obtained by assuming quasi-static flow and taking small time increments. The porous medium adopted for the simulations is a sandpack with porosity 0.395 and grain sizes in the range from 74 to 148 μrn. The effects of the capillary number, Ca, and the viscosity ratio, κ = μo/μw, are studied. The results confirm the importance of the capillary number for displacement, but they also show that for moderate and high Ca values the role of κ is pivotal. When the viscosity ratio is favourable (κ < 1), the microdisplacement efficiency begins to increase rapidly with increasing capillary number for Ca > 10−5, and becomes excellent as Ca → 10−3. On the other hand, when the viscosity ratio is unfavourable (κ > 1), the microdisplacement efficiency begins to improve only for Ca values larger than, say, 5 × 10−4, and is substantially inferior to that achieved with κ < 1 and the same Ca value. In addition to the residual saturation of the non-wetting fluid, the simulator predicts the time required for the displacement, the pattern of the transition zone, the size distribution of the entrapped ganglia, and the acceptance fraction as functions of Ca, κ, and the porous-medium geometry.

Microalgae productive chains are gaining importance as sustainable alternatives to obtain natural pigments. This work presents a review on the most promising pigments and microalgal sources by gathering trends from a 10-year bibliometric survey, a patents search, and an industrial and market analysis built from available market reports, projects and companies’ webpages. The performed analysis pointed out chlorophylls, phycocyanin, astaxanthin, and β-carotene as the most relevant pigments, and Chlorella vulgaris, Spirulina platensis, Haematococcus pluvialis, and Dunaliella salina, respectively, as the most studied sources. Haematococcus is referred in the highest number of patents, corroborating a high technological interest in this microalga. The biorefinery concept, investment in projects and companies related to microalgae cultivation and/or pigment extraction is increasingly growing, particularly, for phycocyanin from Spirulina platensis. These pieces of evidence are a step forward to consolidate the microalgal pigments market, which is expected to grow in the coming years, increasing the prospects of replacing synthetic pigments by natural counterparts.

Dynamic behavior of the flow field in a Reaction Injection Molding, RIM, machine mixing chamber, having dimensions typically used in industrial machines, is studied from dynamic velocity data of Laser Doppler Anemometry, LDA, measurements and Computational Fluid Dynamics, CFD, simulations with a 2D model. This study is based on the spectral analysis of the dynamic flow field data. The typical frequencies, in the reactor flow field, are identified and its values are related to the identified flow structures. The differences between the typical frequencies from experiments and simulations are observed and justified on the basis of the 2D representation of a 3D cylindrical geometry. © 2009 American Institute of Chemical Engineers AIChE J, 2009

No abstract

No abstract