Abstract. Mr= 311.83, triclinic, P1, a=7.3039 (9), b = 7.9432 (9), c = 13.4552 (8)/~, ct= 95.92 (1), fl = 98.66 (1), 7= 99.74 (1) °, V= 753.9 (2)/~3, Z= 2, D x = 1.374 g cm -3, Mo Kct radiation, 2 = 0.71069 ,/k, g= 3.90cm -1, F(000)= 328, room temperature, R = 0.037 for 2430 observed reflections. The CI atom is in an exo and the arylthio group in an endo orientation with respect to the norbornane framework, which has a synchro-twist conformation. Rather high twist angles are probably due to the additivity of the effects of substituents. The short intramolecular S... O distance of 2.643 (2) A corresponds to a secondary interaction and the C-S...O unit is nearly linear.
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