Context. The inner regions of the envelopes surrounding young protostars are characterised by a complex chemistry, with prebiotic molecules present on the scales where protoplanetary disks eventually may form. The Atacama Large Millimeter/submillimeter Array (ALMA) provides an unprecedented view of these regions zooming in on Solar System scales of nearby protostars and mapping the emission from rare species. Aims. The goal is to introduce a systematic survey, "Protostellar Interferometric Line Survey (PILS)", of the chemical complexity of one of the nearby astrochemical templates, the Class 0 protostellar binary IRAS 16293−2422, using ALMA, to understand the origin of the complex molecules formed in its vicinity. In addition to presenting the overall survey, the analysis in this paper focuses on new results for the prebiotic molecule glycolaldehyde, its isomers and rarer isotopologues and other related molecules.Methods. An unbiased spectral survey of IRAS 16293−2422 covering the full frequency range from 329 to 363 GHz (0.8 mm) has been obtained with ALMA, in addition to a few targeted observations at 3.0 and 1.3 mm. The data consist of full maps of the protostellar binary system with an angular resolution of 0.5 (60 AU diameter), a spectral resolution of 0.2 km s −1 and a sensitivity of 4-5 mJy beam −1 km s −1 -approximately two orders of magnitude better than any previous studies. Results. More than 10,000 features are detected toward one component in the protostellar binary, corresponding to an average line density of approximately one line per 3 km s −1 . Glycolaldehyde, its isomers, methyl formate and acetic acid, and its reduced alcohol, ethylene glycol, are clearly detected and their emission well-modeled with an excitation temperature of 300 K. For ethylene glycol both lowest state conformers, aGg and gGg , are detected, the latter for the first time in the ISM. The abundance of glycolaldehyde is comparable to or slightly larger than that of ethylene glycol. In comparison to the Galactic Center these two species are over-abundant relative to methanol, possibly an indication of formation of the species at low temperatures in CO-rich ices during the infall of the material toward the central protostar. Both 13 C and deuterated isotopologues of glycolaldehyde are detected, also for the first time ever in the ISM. For the deuterated species a D/H ratio of ≈5% is found with no differences between the deuteration in the different functional groups of glycolaldehyde, in contrast to previous estimates for methanol and recent suggestions of significant equilibration between water and -OH functional groups at high temperatures. Measurements of the 13 C-species lead to a 12 C: 13 C ratio of ≈30, lower than the typical ISM value. This low ratio may reflect an enhancement of 13 CO in the ice due to either ion-molecule reactions in the gas before freeze-out or differences in the temperatures where 12 CO and 13 CO ices sublimate. Conclusions. The results reinforce the importance of low temperature grain surfac...

We have conducted a survey of 328 protostars in the Orion molecular clouds with the Atacama Large Millimeter/ submillimeter Array at 0.87 mm at a resolution of ∼0 1 (40 au), including observations with the Very Large Array at 9mm toward 148 protostars at a resolution of ∼0 08 (32 au). This is the largest multiwavelength survey of protostars at this resolution by an order of magnitude. We use the dust continuum emission at 0.87 and 9mm to measure the dust disk radii and masses toward the Class 0, Class I, and flat-spectrum protostars, characterizing the evolution of these disk properties in the protostellar phase. The mean dust disk radii for the Class 0, Class I, and flat-spectrum protostars are -+ 44.9 3.4 5.8 , -+ 37.0 3.0 4.9 , and -+ 28.5 2.3 3.7 au, respectively, and the mean protostellar dust disk masses are 25.9 -+ 4.0 7.7 , -+ 14.9 2.2 3.8 , -+11.6 1.93.5 Å M , respectively. The decrease in dust disk masses is expected from disk evolution and accretion, but the decrease in disk radii may point to the initial conditions of star formation not leading to the systematic growth of disk radii or that radial drift is keeping the dust disk sizes small. At least 146 protostellar disks (35% of 379 detected 0.87 mm continuum sources plus 42 nondetections) have disk radii greater than 50 au in our sample. These properties are not found to vary significantly between different regions within Orion. The protostellar dust disk mass distributions are systematically larger than those of Class II disks by a factor of >4, providing evidence that the cores of giant planets may need to at least begin their formation during the protostellar phase.

Context. One of the important questions of astrochemistry is how complex organic molecules, including potential prebiotic species, are formed in the envelopes around embedded protostars. The abundances of minor isotopologues of a molecule, in particular the Dand 13 C-bearing variants, are sensitive to the densities, temperatures and time-scales characteristic of the environment in which they form, and can therefore provide important constraints on the formation routes and conditions of individual species. Aims. The aim of this paper is to systematically survey the deuteration and the 13 C content of a variety of oxygen-bearing complex organic molecules on Solar System scales toward the "B component" of the protostellar binary IRAS 16293-2422. Methods. We use the data from an unbiased molecular line survey of the protostellar binary IRAS 16293−2422 between 329 and 363 GHz from the Atacama Large Millimeter/submillimeter Array (ALMA). The data probe scales of 60 AU (diameter) where most of the organic molecules are expected to have sublimated off dust grains and be present in the gas-phase. The deuterated and 13 Cisotopic species of ketene, acetaldehyde and formic acid, as well as deuterated ethanol, are detected unambiguously for the first time in the interstellar medium. These species are analysed together with the 13 C isotopic species of ethanol, dimethyl ether and methyl formate along with mono-deuterated methanol, dimethyl ether and methyl formate. Results. The complex organic molecules can be divided into two groups with one group, the simpler species, showing a D/H ratio of ≈ 2% and the other, the more complex species, D/H ratios of 4-8%. This division may reflect the formation time of each species in the ices before or during warm-up/infall of material through the protostellar envelope. No significant differences are seen in the deuteration of different functional groups for individual species, possibly a result of the short time-scale for infall through the innermost warm regions where exchange reactions between different species may be taking place. The species show differences in excitation temperatures between 125 K and 300 K. This likely reflects the binding energies/sublimation temperatures of the individual species, in good agreement to what has previously been found for high-mass sources. For dimethyl ether the 12 C/ 13 C ratio is found to be lower by up to a factor of 2 compared to typical ISM values similar to what has previously been inferred for glycolaldehyde. Tentative identifications suggest that the same may apply for 13 C isotopologues of methyl formate and ethanol. If confirmed, this may be a clue to their formation at the late prestellar/early protostellar phases with an enhancement of the available 13 C relative to 12 C related to small differences in binding energies for CO isotopologues or the impact of FUV irradiation by the central protostar.Conclusions. The results point to the importance of ice surface chemistry for the formation of these complex organic molecules at different stag...

astroquery is a collection of tools for requesting data from databases hosted on remote servers with interfaces exposed on the internet, including those with web pages but without formal application program interfaces (APIs). These tools are built on the Python requests package, which is used to make HTTP requests, and astropy, which provides most of the data parsing functionality. astroquery modules generally attempt to replicate the web page interface provided by a given service as closely as possible, making the transition from browser-based to command-line interaction easy. astroquery has received significant contributions from throughout the astronomical community, including several significant contributions from telescope archives. astroquery enables the creation of fully reproducible workflows from data acquisition through publication. This paper describes the philosophy, basic structure, and development model of the astroquery package. The complete documentation for astroquery can be found at

Binary and multiple star systems are a frequent outcome of the star formation process 1;2 , and as a result, almost half of all sun-like stars have at least one companion star 3 . Theoretical studies indicate that there are two main pathways that can operate concurrently to form binary/multiple star systems: large scale fragmentation of turbulent gas cores and filaments 4;5 or smaller scale fragmentation of a massive protostellar disk due to gravitational instability 6;7 . Observational evidence for turbulent fragmentation on scales of >1000 AU has recently emerged 8;9 . Previous evidence for disk fragmentation was limited to inferences based on the separations of more-evolved pre-main sequence and protostellar multiple systems 10;11;12;13 . The triple protostar system L1448 IRS3B is an ideal candidate to search for evidence of disk fragmentation. L1448 IRS3B is in an early phase of the star formation process, likely less than 150,000 years in age 14 , and all protostars in the system are separated by <200 AU. Here we report observations of dust and molecular gas emission that reveal a disk with spiral structure surrounding the three protostars. Two protostars near the center of the disk are separated by 61 AU, and a tertiary protostar is coincident with a spiral arm in the outer disk at a 183 AU separation 13 . The inferred mass of the central pair of protostellar objects is ⇠1 M , while the disk surrounding the three protostars has a total mass of ⇠0.30 M . The tertiary protostar itself has a minimum mass of ⇠0.085 M . We demonstrate that the disk around L1448 IRS3B appears susceptible to disk fragmentation at radii between 150 AU and 320 AU, overlapping with the location of the tertiary protostar. This is consistent with models for a protostellar disk that has recently undergone gravitational instability, spawning one or two companion stars.L1448 IRS3B is located in the Perseus molecular cloud at a distance of ⇠230 pc 15 and contains three protostars out of the six that collectively make up L1448 IRS3 13;14 , spanning 0.05 pc. L1448 IRS3B is a Class 0 protostar system 16 , which signifies an early phase of the star formation process when the protostars are deeply enshrouded in an envelope of accreting material 17 . The three protostars in L1448 IRS3B (denoted -a, -b, and -c) have a hierarchical configuration; the central-most protostar, IRS3B-a, has projected separations from IRS3B-b and IRS3B-c of 61 AU and 183 AU, respectively 13 . The new observations of L1448 IRS3B conducted with the Atacama Large Millimeter/submillimeter Array (ALMA) at a resolution of 0. 00 27⇥0. 00 16 (62 AU ⇥ 37 AU) provide images at 1.3 mm of the dust and gas emission surrounding the three protostars with 10⇥ higher sensitivity and 2⇥ higher resolution than previous studies.The ALMA 1.3 mm image of L1448 IRS3B is shown in Figure 1, revealing dust emission toward each of the three distinct protostars identified in previous Karl G. Jansky Very Large Array (VLA) observations 13 . The ALMA images also reveal a disk with substructure sur...