Radium analysis is carried out by batch adsorption from natural waters on basic lead rhodizonate supported on charcoal, LERHO, starting from 2-L samples. 133Ba is added to allow the measurement of the overall chemical yield by gamma counting. Radium is recovered with a few milliliters of 1.5 M HCl, and lead is removed by a chromatographic column filled with Dowex 2 x 8. Finally 50 micrograms of barium carrier is added, and the radium is coprecipitated as sulfate on a preformed bed of barium sulfate, to prepare a sample suitable for alpha and gamma counting. The detection limit of the proposed method is 0.002 Bq/L 226Ra. This value is far beyond the radium activity admissible for drinking waters. Due to lack of appropriate samples, the procedure was tested using mineral waters spiked with 226Ra and two commercially available mineral waters with very low radium contents.
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