The asymptotic properties of the reaction front formed in a reversible reaction-diffusion process A+B<-->C (static) with initially separated reactants are investigated. The case of arbitrary nonzero values of the diffusion constants D(A) and D(B) and initial concentrations a(0) and b(0) of the reactants A and B is considered. The system is studied in the limit of t-->infinity and g-->0, where t and g are the time and the backward reaction rate constant, respectively. The dynamics of the reaction front is described as a crossover between the "irreversible" regime at times t<>g(-1). The general properties of the crossover are studied with the help of an extended scaling approach formulated in this work. On the basis of the mean-field equations the analytical solutions in the reversible regime t>>g(-1) inside the reaction zone are discussed. It is shown that in the immobile reaction zone the reaction rate profile has two distinct maxima. This profile differs drastically from the usual single-maximum reaction rate profile inherent in the mobile reaction zone. The two-hump reaction zone profile is the result of the influence of C on the reaction rate in the reversible regime. Numerical computation of the mean-field kinetics equations supports the results of the asymptotic consideration.
We study theoretically and numerically the irreversible A+B-->0 reaction-diffusion process of initially separated reactants occupying the regions of lengths LA, LB comparable with the diffusion length (LA,LB approximately sqrt[Dt], here D is the diffusion coefficient of the reactants). It is shown that the process can be divided into two stages in time. For t<L2/D these are well-approximated by exponential laws. The reaction-diffusion process of about 0.5 of initial quantities of reactants is described by the obtained exponential laws. Our theoretical predictions show good agreement with numerical simulations.
We study the properties of the reaction front formed in a reversible reaction diffusion process A+B<-->C, with initially separated reactants. The case of the mobile C component is considered. In accordance with Chopard et al. [Phys. Rev. E 47, R40 (1993)] the dynamics of the front is described as a crossover between the "irreversible" regime at short times and the "reversible" regime at long times. A refined definition for the rate of C production is suggested, taking into account both the forward and the backward reaction rates. By this definition within the framework of the mean-field equations it is shown that the reversible regime is characterized by scaling of the local rate of C production as R(local) approximately t(-1) and by scaling of the global rate of C production as R(global) approximately t(-1/2). It is also established that in the considered special case of equal diffusion coefficients and equal initial concentrations, the macroscopic properties of the reaction front, such as the global rate of the C production R(global) and the concentration profiles of the components outside the front reaction, are unchanged through this crossover.
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