136ChemInform Abstract The adamantylidenexanthenyl phosphate (I) is converted to the 1,2-dioxetane (II) by singlet oxygenation. The alkaline phosphatase-induced decomposition of (II), yielding (III) and (IV), is accompanied by the emission of light.
In Abhängigkeit von ihren Oxidationspotentialen lassen sich Bpoxide entweder nur mit DCA [(ld), (VI)/(VII), (XIII)/(XIV)] oder in Gegenwart von Biphenyl als Co‐Sensibilisator [(1), (III)/(IV), (lX)/(X)] durch Photooxidation in entsprechende Ozonide überführen.
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