Context. Carbon monosulphide (CS) is among the most abundant gas-phase S-bearing molecules in cold dark molecular clouds. It is easily observable with several transitions in the millimeter wavelength range, and has been widely used as a tracer of the gas density in the interstellar medium in our Galaxy and external galaxies. However, chemical models fail to account for the observed CS abundances when assuming the cosmic value for the elemental abundance of sulfur. Aims. The CS+O → CO + S reaction has been proposed as a relevant CS destruction mechanism at low temperatures, and could explain the discrepancy between models and observations. Its reaction rate has been experimentally measured at temperatures of 150−400 K, but the extrapolation to lower temperatures is doubtful. Our goal is to calculate the CS+O reaction rate at temperatures <150 K which are prevailing in the interstellar medium. Methods. We performed ab initio calculations to obtain the three lowest potential energy surfaces (PES) of the CS+O system. These PESs are used to study the reaction dynamics, using several methods (classical, quantum, and semiclassical) to eventually calculate the CS + O thermal reaction rates. In order to check the accuracy of our calculations, we compare the results of our theoretical calculations for T ~ 150−400 K with those obtained in the laboratory. Results. Our detailed theoretical study on the CS+O reaction, which is in agreement with the experimental data obtained at 150–400 K, demonstrates the reliability of our approach. After a careful analysis at lower temperatures, we find that the rate constant at 10 K is negligible, below 10−15 cm3 s−1, which is consistent with the extrapolation of experimental data using the Arrhenius expression. Conclusions. We use the updated chemical network to model the sulfur chemistry in Taurus Molecular Cloud 1 (TMC 1) based on molecular abundances determined from Gas phase Elemental abundances in Molecular CloudS (GEMS) project observations. In our model, we take into account the expected decrease of the cosmic ray ionization rate, ζH2, along the cloud. The abundance of CS is still overestimated when assuming the cosmic value for the sulfur abundance.

Gas phase Elemental abundances in Molecular CloudS (GEMS) is an IRAM 30 m Large Program designed to provide estimates of the S, C, N, and O depletions and gas ionization degree, X(e−), in a selected set of star-forming filaments of Taurus, Perseus, and Orion. Our immediate goal is to build up a complete and large database of molecular abundances that can serve as an observational basis for estimating X(e−) and the C, O, N, and S depletions through chemical modeling. We observed and derived the abundances of 14 species (13CO, C18O, HCO+, H13CO+, HC18O+, HCN, H13CN, HNC, HCS+, CS, SO, 34SO, H2S, and OCS) in 244 positions, covering the AV ~3 to ~100 mag, n(H2) ~ a few 103 to 106 cm−3, and Tk ~10 to ~30 K ranges in these clouds, and avoiding protostars, HII regions, and bipolar outflows. A statistical analysis is carried out in order to identify general trends between different species and with physical parameters. Relations between molecules reveal strong linear correlations which define three different families of species: (1) 13CO and C18O isotopologs; (2) H13CO+, HC18O+, H13 CN, and HNC; and (3) the S-bearing molecules. The abundances of the CO isotopologs increase with the gas kinetic temperature until TK ~ 15 K. For higher temperatures, the abundance remains constant with a scatter of a factor of ~3. The abundances of H13 CO+, HC18 O+, H13 CN, and HNC are well correlated with each other, and all of them decrease with molecular hydrogen density, following the law ∝ n(H2)−0.8 ± 0.2. The abundances of S-bearing species also decrease with molecular hydrogen density at a rate of (S-bearing/H)gas ∝ n(H2)−0.6 ± 0.1. The abundances of molecules belonging to groups 2 and 3 do not present any clear trend with gas temperature. At scales of molecular clouds, the C18O abundance is the quantity that better correlates with the cloud mass. We discuss the utility of the 13CO/C18O, HCO+/H13CO+, and H13 CO+/H13CN abundance ratios as chemical diagnostics of star formation in external galaxies.

The Stephan's Quintet (SQ) is a famous interacting compact group of galaxies in an important stage of dynamical evolution, but surprisingly very few spectroscopic studies are found in the literature. We present optical integral field spectroscopy (IFS) observations of the SQ from the PPAK IFS Nearby Galaxies Survey (PINGS), that provide a powerful way of studying with spatial resolution the physical characteristics of the ionized gas within the group. The nature of the gas emission is analysed using 2D maps of continuum-subtracted, pure emission-line intensities, stacked spectra, diagnostic diagrams, and photoionization model predictions. In the case of NGC 7319, we study the galaxy-wide high-velocity outflow emission by comparing the emission properties with theoretical shock and AGN models. We conclude that the excitation mechanism of the gas in this galaxy is a mixture of AGN photoionization and shocks with a photoionizing precursor. The emission spectra from the large scale shock front in the interacting pair NGC 7318A/B is analysed, confirming the presence of several kinematic components. Comparison with predictions from theoretical shock models suggests that the gas emission is consistent with shocks without a photoionizing precursor, low pre-shock density, and velocities in the range of ∼ 200 − 400 km s −1 . The gas oxygen abundance for NGC 7318B is determined using an updated O3N2 calibration. Although NGC 7317 shows no significant gas emission, an ionizing cluster is found southwest of this galaxy, probably the result of tidal interaction. As a by-product, we analyse the gas emission of the foreground galaxy NGC 7320.

Context. Methanol, one of the simplest complex organic molecules in the interstellar medium, has been shown to be present and extended in cold environments such as starless cores. Studying the physical conditions at which CH3OH starts its efficient formation is important to understand the development of molecular complexity in star-forming regions. Aims. We aim to study methanol emission across several starless cores and investigate the physical conditions at which methanol starts to be efficiently formed, as well as how the physical structure of the cores and their surrounding environment affect its distribution. Methods. Methanol and C18O emission lines at 3 mm have been observed with the IRAM 30 m telescope within the large programme Gas phase Elemental abundances in Molecular CloudS towards 66 positions across 12 starless cores in the Taurus Molecular Cloud. A non-LTE (local thermodynamic equilibrium) radiative transfer code was used to compute the column densities in all positions. We then used state-of-the-art chemical models to reproduce our observations. Results. We have computed N(CH3OH)/N(C18O) column density ratios for all the observed offsets, and the following two different behaviours can be recognised: the cores where the ratio peaks at the dust peak and the cores where the ratio peaks with a slight offset with respect to the dust peak (~10 000 AU). We suggest that the cause of this behaviour is the irradiation on the cores due to protostars nearby which accelerate energetic particles along their outflows. The chemical models, which do not take irradiation variations into account, can reproduce the overall observed column density of methanol fairly well, but they cannot reproduce the two different radial profiles observed. Conclusions. We confirm the substantial effect of the environment on the distribution of methanol in starless cores. We suggest that the clumpy medium generated by protostellar outflows might cause a more efficient penetration of the interstellar radiation field in the molecular cloud and have an impact on the distribution of methanol in starless cores. Additional experimental and theoretical work is needed to reproduce the distribution of methanol across starless cores.

Context. Gas phase Elemental abundances in molecular CloudS (GEMS) is an IRAM 30m large program aimed at determining the elemental abundances of carbon (C), oxygen (O), nitrogen (N), and sulfur (S) in a selected set of prototypical star-forming filaments. In particular, the elemental abundance of S remains uncertain by several orders of magnitude, and its determination is one of the most challenging goals of this program. Aims. This paper aims to constrain the sulfur elemental abundance in Taurus, Perseus, and Orion A based on the GEMS molecular database. The selected regions are prototypes of low-mass, intermediate-mass, and high-mass star-forming regions, respectively, providing useful templates for the study of interstellar chemistry. Methods. We have carried out an extensive chemical modeling of the fractional abundances of CO, HCO + , HCN, HNC, CS, SO, H 2 S, OCS, and HCS + to determine the sulfur depletion toward the 244 positions in the GEMS database. These positions sample visual extinctions from A V ∼ 3 mag to >50 mag, molecular hydrogen densities ranging from a few ×10 3 cm −3 to 3×10 6 cm −3 , and T k ∼ 10−35 K. We investigate the possible relationship between sulfur depletion and the grain charge distribution in different environments. Results. Most of the positions in Taurus and Perseus are best fitted assuming early-time chemistry, t=0.1 Myr, ζ H 2 ∼ (0.5−1)×10 −16 s −1 , and [S/H]∼1.5×10 −6 . On the contrary, most of the positions in Orion are fitted with t=1 Myr and ζ H 2 ∼ 10 −17 s −1 . Moreover, ∼40% of the positions in Orion are best fitted assuming the undepleted sulfur abundance, [S/H]∼1.5×10 −5 . We find a tentative trend of sulfur depletion increasing with density. Conclusions. Our results suggest that sulfur depletion depends on the environment. While the abundances of sulfur-bearing species are consistent with undepleted sulfur in Orion, a depletion factor of ∼20 is required to explain those observed in Taurus and Perseus. We propose that differences in the grain charge distribution might explain these variations. Grains become negatively charged at a visual extinction of A V ∼ 3.5 mag in Taurus and Perseus. At this low visual extinction, the S + abundance is high, X(S + )>10 −6 , and the electrostatic attraction between S + and negatively charged grains could contribute to enhance sulfur depletion. In Orion, the net charge of grains remains approximately zero until higher visual extinctions (A V ∼ 5.5 mag), where the abundance of S + is already low because of the higher densities, thus reducing sulfur accretion. The shocks associated with past and ongoing star formation could also contribute to enhance [S/H].