Three-dimensional structures capable of reversible changes in shape, i.e., four-dimensional-printed structures, may enable new generations of soft robotics, implantable medical devices, and consumer products. Here, thermally responsive liquid crystal elastomers (LCEs) are direct-write printed into 3D structures with a controlled molecular order. Molecular order is locally programmed by controlling the print path used to build the 3D object, and this order controls the stimulus response. Each aligned LCE filament undergoes 40% reversible contraction along the print direction on heating. By printing objects with controlled geometry and stimulus response, magnified shape transformations, for example, volumetric contractions or rapid, repetitive snap-through transitions, are realized.
Three-dimensional structures that undergo reversible shape changes in response to mild stimuli enable a wide range of smart devices, such as soft robots or implantable medical devices. Herein, a dual thiol-ene reaction scheme is used to synthesize a class of liquid crystal (LC) elastomers that can be 3D printed into complex shapes and subsequently undergo controlled shape change. Through controlling the phase transition temperature of polymerizable LC inks, morphing 3D structures with tunable actuation temperature (28 ± 2 to 105 ± 1 °C) are fabricated. Finally, multiple LC inks are 3D printed into single structures to allow for the production of untethered, thermo-responsive structures that sequentially and reversibly undergo multiple shape changes.
Light is distinguished as a contactless energy source for microscale devices as it can be directed from remote distances, rapidly turned on or off, spatially modulated across length scales, polarized, or varied in intensity. Motivated in part by these nascent properties of light, transducing photonic stimuli into macroscopic deformation of materials systems has been examined in the last half-century. Here we report photoinduced motion (photomotility) in monolithic polymer films prepared from azobenzene-functionalized liquid crystalline polymer networks (azo-LCNs). Leveraging the twisted-nematic orientation, irradiation with broad spectrum ultraviolet–visible light (320–500 nm) transforms the films from flat sheets to spiral ribbons, which subsequently translate large distances with continuous irradiation on an arbitrary surface. The motion results from a complex interplay of photochemistry and mechanics. We demonstrate directional control, as well as climbing.
The ability to pattern material response, voxel by voxel, to direct actuation and manipulation in macroscopic structures can enable devices that utilize ambient stimuli to produce functional responses at length scales ranging from the micro- to the macroscopic. Fabricating liquid crystalline polymers (LCPs), where the molecular director is indexably defined in three-dimensional (3D) freeforms, can be a key enabler. Here, the combination of anisotropic magnetic susceptibility of the liquid crystalline monomers in a reorientable magnetic field and spatially selective photopolymerization using a digital micromirror device to independently define molecular orientation in light and/or heat-responsive multimaterial elements, which are additively incorporated into 3D freeforms, is exploited. This is shown to enable structural complexity across length scales in nontrivial geometries, including re-entrant shapes, which are responsive to either heat or light. A range of monomer compositions are optimized to include photoinitiators, light absorbers, and polymerization inhibitors to modulate the polymerization characteristics while simultaneously retaining the tailorability of the nematic alignment. The versatility of this framework is illustrated in an array of examples, including (i) thermomechanical generation of Gaussian-curved structures from flat geometries, (ii) light-responsive freeform topographies, and (iii) multiresponsive manipulators, which can be powered along independent axes using heat and/or light. The ability to integrate responses to multiple stimuli, where the principal directions of the mechanical output are arbitrarily tailored in a 3D freeform, enables new design spaces in soft robotics, micromechanical/fluidic systems, and optomechanical systems.
Measurement of strain field in the primary deformation zone is of major interest for development of machining as an experimental technique for studying phenomena associated with large strain deformation. A study has been made of the primary deformation zone and tool-chip interface in planestrain (two-dimensional) machining of metals. The use of a high-speed, charge-coupled device (CCD) imaging system in conjunction with an optically transparent, sapphire cutting tool has enabled characteristics of the deformation field such as velocity, strain, and material flow, to be obtained at high spatial and temporal resolution. The velocity distributions in the primary deformation zone and along the tool rake face have been obtained by applying a particle image velocimetry (PIV) technique to sequences of high-speed images of the chip-tool interface taken through the transparent tool, and of the primary deformation zone recorded from a side of the workpiece. A procedure is presented and demonstrated for determining the strain and strain rate distributions in the primary deformation zone. The measurements have provided data about the variations of velocity, strain rate, and strain, in and around the cutting edge and primary deformation zone; confirmed the existence of a region of retarded sliding in the region of intimate contact between tool and chip; and highlighted the occurrence of a region of dead metal ahead of the cutting edge when cutting with a negative rake angle tool.
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