Abstract

We consider the effect of droplet geometry on the early-stages of coffee-ring formation during the evaporation of a thin droplet with an arbitrary simple, smooth, pinned contact line. We perform a systematic matched asymptotic analysis of the small capillary number, large solutal Péclet number limit for two different evaporative models: a kinetic model, in which the evaporative flux is effectively constant across the droplet, and a diffusive model, in which the flux is singular at the contact line. For both evaporative models, solute is transported to the contact line by a capillary flow in the droplet bulk, while local to the contact line, solute diffusion counters advection. The resulting interplay leads to the formation of the nascent coffee-ring profile. By exploiting a coordinate system embedded in the contact line, we solve explicitly the local leading-order problem, deriving a similarity profile (in the form of a gamma distribution) that describes the nascent coffee ring. Notably, for an arbitrary contact line geometry, the ring characteristics change due to the concomitant asymmetry in the shape of the droplet free surface, the evaporative flux (for diffusive evaporation) and the mass flux into the contact line. We utilize the asymptotic model to determine the effects of contact line geometry on the growth of the coffee ring for a droplet with an elliptical contact set. Our results offer mechanistic insight into the effect of contact line curvature on the development of the coffee ring from deposition up to jamming of the solute; moreover, our model predicts when finite concentration effects become relevant.

This paper extends Wagner theory for the ideal, incompressible normal impact of rigid bodies that are nearly parallel to the surface of a liquid half-space. The impactors considered are three-dimensional and have an oblique impact velocity. A variational formulation is used to reveal the relationship between the oblique and corresponding normal impact solutions. In the case of axisymmetric impactors, several geometries are considered in which singularities develop in the boundary of the effective wetted region. We present the corresponding pressure profiles and models for the splash sheets.Key words: Authors should not enter keywords on the manuscript, as these must be chosen by the author during the online submission process and will then be added during the typesetting process (see http://journals.cambridge.org/data/relatedlink/jfmkeywords.pdf for the full list)

We perform a thorough qualitative and quantitative comparison of theoretical predictions and direct numerical simulations for the two-dimensional, vertical impact of two droplets of the same fluid. In particular, we show that the theoretical predictions for the location and velocity of the jet root are excellent in the early stages of the impact, while the predicted jet velocity and thickness profiles are also in good agreement with the computations before the jet begins to bend. By neglecting the role of the surrounding gas both before and after impact, we are able to use Wagner theory to describe the early-time structure of the impact. We derive the model for general droplet velocities and radii, which encompasses a wide range of impact scenarios from the symmetric impact of identical drops to liquid drops impacting a deep pool. The leading-order solution is sufficient to predict the curve along which the root of the high-speed jet travels. After moving into a frame fixed in this curve, we are able to derive the zero-gravity shallow-water equations governing the leading-order thickness and velocity of the jet. Our numerical simulations are performed in the open-source software Gerris, which allows for the level of local grid refinement necessary for a problem with such a wide variety of length scales. The numerical simulations incorporate more of the physics of the problem, in particular the surrounding gas, the fluid viscosities, gravity and surface tension. We compare the computed and predicted solutions for a range of droplet radii and velocities, finding excellent agreement in the early stage. In light of these successful comparisons, we discuss the tangible benefits of using Wagner theory to confidently track properties such as the jet-root location, jet thickness and jet velocity in future studies of splash jet/ejecta evolution.