The suitability of groundwater quality of 22 wells located in the rural areas surrounding Ingaldhal defunct copper mine in Chithradurga district of Karnataka state was assessed for drinking purpose based on the various water quality parameters. Standard methods for physicochemical analysis of groundwater samples were employed. The results of analysis carried out showed the following concentration ranges: pH (7.61-8.34), EC (950-3120μS/cm), TH (410-1400mg/l), TDS (594-1913mg/l), F -(0.15-1.43mg/l), NO 3 -(14-162mg/l), HCO 3 -(417-574mg/l), SO 4 2-(68-286mg/l) and Ca 2+ (59-150mg/l), Mg 2+ (49-250mg/l), Na + (38-290mg/l), K + (6-58mg/l). The ionic dominance for the major cations and the anions respectively were in the order of Mg 2+ > Na + > Ca 2+ > K + and HCO 3 -> Cl -> SO 4 2-> NO 3 -> Fe -> F -> CO 3 -. Most of the samples analyzed were above the Guidelines set by both national (BIS) and international (WHO, 2011) bodies for drinking water. Geographical Information System (GIS) capabilities are used to classify zones with acceptable groundwater quality for drinking purpose. The Gibbs diagrams show that the groundwater samples fall both in the rock and evaporation dominance fields as well as about 18% samples fall outside the defined fields indicating integrated mechanisms for hydrochemistry such as high weathering and low rates of evaporation in addition to input from the anthropogenic activities. According to plots on the piper diagram the groundwater of the Ingaldhal and surrounding regions consists of 4 hydrochemical types, viz., Ca-Mg-HCO 3 type (n=9), Ca-Mg-SO 4 (n=6), mixed Ca-Na-HCO 3 (n=6) and Na-Cl type (n=1). Assessment of groundwater samples from various parameters indicates that groundwater in most part of the study area is chemically unsuitable for drinking purpose.

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Hydrogeochemical data of groundwater from the semi-confined aquifer of a coastal two-tier aquifer in Amol-Ghaemshahr plain, Mazandaran Province, Northern Iran reveal salinization of the fresh groundwater (FGW). The saline groundwater zone is oriented at an angle to both Caspian Sea coastline and groundwater flow direction and extends inland from the coastline for more than 40 km. Spearman's rank correlation coefficient matrices, factor analysis data, and values of C ratio, chloro-alkaline indices, and Na(+)/Cl(-) molar ratio indicate that the ionic load in the FGW is derived essentially from carbonic acid-aided weathering of carbonates and aluminosilicate minerals, relict connate saline water, and ion exchange reactions. Saline groundwater samples (SGWS) (n = 20) can be classified into two groups. SGWS of group 1 (n = 17) represent the saline groundwater zone below the Caspian Sea level, and salinization is attributed essentially to (1) lateral intrusion of Caspian seawater as a consequence of (a) excessive withdrawal of groundwater from closely spaced bore wells located in the eastern part of the coastal zone and (b) imbalance between recharge and discharge of the two-tier aquifer and (2) upconing of paleobrine (interfaced with FGW) along deep wells. SGWS of this group contain, on average, 7.9% of saltwater, the composition of which is similar to that of Caspian seawater. SGWS of group 2 (n = 3) belong to the saline groundwater zone encountered above the Caspian Sea level, and salinization of the groundwater representing these samples is attributed to irrigation return flow (n = 2) and inflow of saline river water (n = 1).

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