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The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, the hydration of nitriles to the corresponding carboxamides by use of ruthenium(II) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand.

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Synthesis of Bis(glycosylamino)alkanes and Bis(glycosylamino)arenes. -Condensation of D-mannose and D-galactose with aliphatic and aromatic diamines affords the corresponding bis(glycosylamino)alkanes and bis(glycosylamino)arenes in good yields. -(METLITSKIKH*, S. V.; KOROTEEV, A. M.; KOROTEEV, M. P.; SHASHKOV, A. S.; KORLYUKOV, A. A.; ANTIPIN, M. Y.; STASH, A. I.; NIFANTIEV, E. E.; Russ. Chem. Bull. 54 (2005) 12, 2890-2898; Moscow Pedagog. State Univ., Moscow 119021, Russia; Eng.) -D. Singer 44-190

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