Eco-friendly inorganic halide perovskite materials with numerous structural configurations and compositions are now in the leading place of researcher’s attention for outstanding photovoltaic and optoelectronic performance. In the present approach, density functional theory calculations have been performed to explore the structural, mechanical, electronic, and optical properties of perovskite-type CsGeCl3 under various hydrostatic pressures, up to 10 GPa. The result shows that the optical absorption and conductivity are directed toward the low-energy region (red shift) remarkably with increasing pressure. The analysis of mechanical properties certifies that CsGeCl3 has ductile entity and the ductile manner has increasing affinity with applied pressure. The decreasing affinity of the bandgap is also perceived with applied pressure, which notifies that the performance of the optoelectronic device can be tuned and developed under pressure.
A comparative study on mechanical, thermodynamic, electronic, and optical properties has been performed on various compounds having an ABO3, where A = Ba, Ca, Sr and B = Ce, Ti, Zr, perovskite structure using first-principles calculations. These materials’ properties have been thoroughly investigated for their ground states under the same computational parameters. The computed lattice parameters in the ground state agreed with other theoretical studies. Elastic moduli, ductility or brittleness, elastic anisotropy, mechanical stability, and stiffness of solid materials are studied. Enthalpy (H), entropy (S), and free energy (F) were reported from the vibrational properties of the materials. The temperature-dependent heat capacity and Debye temperature are investigated. The electronic band structure as a function of energy, of different perovskite structures at the ground state, is also studied. From this study, the ABO3 perovskite has emerged as the most promising material for applications in optoelectronics, photonics, and mechanical and thermoelectric devices.
Eleven batches of white bread containing 0-1.92g of dimethyl fumarate (DMF) or calcium propionate (CP) per kg flour were prepared by a sponge dough formulation. The loaves were packaged in polyethylene bags, stored at 22-23°C and 4555% R.H., and periodically observed for visible signs of mold growth. The moldfree shelf-lives of loaves containing CP ranged from 16-30 days. Loaves containing 0.32g or more of DMF per kg flour exhibited no mold growth during 475 days of storage. The quality characteristics of loaves containing DMF, as determined by volume, firmness, % moisture, water activity and sensory evaluation were similar to those of loaves containing CP.
The vehicle routing problem (VRP) is a widely studied combinatorial optimization problem. We introduce a variant of the multidepot and periodic VRP (MDPVRP) and propose a heuristic initialized stochastic memetic algorithm to solve it. The main challenge in designing such an algorithm for a large combinatorial optimization problem is to avoid premature convergence by maintaining a balance between exploration and exploitation of the search space. We employ intelligent initialization and stochastic learning to address this challenge. The intelligent initialization technique constructs a population by a mix of random and heuristic generated solutions. The stochastic learning enhances the solutions' quality selectively using simulated annealing with a set of random and heuristic operators. The hybridization of randomness and greediness in the initialization and learning process helps to maintain the balance between exploration and exploitation. Our proposed algorithm has been tested extensively on the existing benchmark problems and outperformed the baseline algorithms by a large margin. We further compared our results with that of the state-of-the-art algorithms working under MDPVRP formulation and found a significant improvement over their results.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.