The present article describes CoxFe3−xO4 films, which were fabricated at 90 °C by the ferrite-plating method and have the excellent perpendicular magnetic anisotropy and the perpendicular coercivity Hc⊥ above 2 kOe. The films were composed of Co ferrite and Fe3O4 grains. The highest Hc⊥ reached 3 kOe at the composition of Co0.43Fe2.57O4 and the saturation magnetization Ms was 500–550 emu/cc. Hc⊥ was over 2 kOe even for a film thickness of 35 nm without any underlayers. ΔM⊥ evaluation that is measured in the perpendicular direction to the film plane showed that the interactions in the films supported the magnetized state, stabilizing the direct current remanent state. The Mössbauer analyses revealed that the Co0.43Fe2.57O4 films have excellent perpendicular magnetic anisotropy and the magnetization direction inclined from the perpendicular axis due to the demagnetization field. This achievement will open the way to develop the high-density perpendicular recording media even when plastic disks and sheets are used as substrates.

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The authors have prepared Ba–ferrite film disks and evaluated their magnetic read/write characteristics. The c-axis-oriented Ba–ferrite thin films were formed epitaxially on c-axis-oriented ZnO films by means of a targets-facing-type sputtering system. The direction of easy magnetization in the film with perpendicular crystalline anisotropy is almost perpendicular to the film plane. Thus, the perpendicular remanence is more than 60 times as large as the in-plane one. The simple Ba–ferrite films, however, have a coercive force, Hc⊥ above 2 kOe which is too large to write on by means of a conventional head. The substitution of In3+ in the Ba–ferrite films makes the Hc⊥ values decrease to about 1 kOe without increasing the critical temperature, Tcritical, of c-axis orientation. The read/write characteristics of the films were measured with a MnZn–ferrite ring head. The reproduced signal exhibits clear dipulsive waveforms as the dipulse ratio exceeds 0.7. Furthermore, the overwrite ratio decreases below −28 dB for the In3+-substituted Ba-ferrite film disk. The Ba–ferrite film disks have promising potential as a high-density perpendicular magnetic recording medium.

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An anomalous Hall effect (AHE) and a planar Hall effect (PHE) represent a perpendicular component and an in-plane component of the magnetization in the double-layered media. Since AHE and PHE have different symmetries regarding to the applied magnetic field H, it is easy to distinguish the AHE component, which is proportional to M, and PHE component, which is proportional to M2, from the measured Hall voltage VH. The Hall voltage of the double-layered film composed of Co–Cr–Ta and Ni–Fe layers was observed when the magnetic field is applied at an angle (α) of 30° from the normal to the film plane. The perpendicular and the in-plane components, which are regarded as the magnetization process of Co–Cr–Ta and that of the Ni–Fe layer, respectively, can be easily determined from these characteristics. The Hall measurement is useful to study the magnetization characteristics in the double-layered media.

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Studies on the thermal release of krypton from rf sputterdeposited amorphous Gd-Co films by a UHV mass spectrometric technique