Within the silicon photovoltaics (PV) community, there are many approaches, tools, and input parameters for simulating solar cells, making it difficult for newcomers to establish a complete and representative starting point and imposing high requirements on experts to tediously state all assumptions and inputs for replication. In this review, we address these problems by providing complete and representative input parameter sets to simulate six major types of crystalline silicon solar cells. Where possible, the inputs are justified and up-to-date for the respective cell types, and they produce representative measurable cell characteristics. Details of the modeling approaches that can replicate the simulations are presented as well. The input parameters listed here provide a sensible and consistent reference point for researchers on which to base their refinements and extensions.
Passivated emitter and rear cell (PERC) solar cells are currently being introduced into mass production. In this paper, we report a novel PERC solar cell design that applies a screen-printed rear Al finger grid instead of the conventional full-area aluminum (Al) rear layer while using the same PERC manufacturing sequence. We name this novel cell concept PERC+ because it offers several advantages. In particular, the Al paste consumption of the PERC+ cells is drastically reduced to 0.15 g instead of 1.6 g for the conventional PERC cells. The Al fingers create 2-μm-deeper aluminum back surface fields, which increases the open-circuit voltage by 4 mV. The five-busbar Al finger grid enables bifacial applications of the PERC+ cells with front-side efficiencies up to 20.8% and rear-side efficiencies up to 16.5% measured with a black chuck. The corresponding bifaciality is 79%. When applied in monofacial modules where the white back sheet acts as external rear reflector, the efficiency of the PERC+ cells is estimated to 20.9%, which is comparable with conventional PERC cells. Whereas Institute for Solar Energy Research Hamelin developed the aforementioned PERC+ results, SolarWorld independently pioneered a very similar bifacial PERC+ cell process starting in 2014. Transfer into mass production has been successfully accomplished, and novel glass-glass bifacial PERC+ modules have been launched at the Intersolar 2015 based on a most simple, lean, and cost-effective bifacial cell process. These new bifacial PERC+ modules show an increase in annual energy yield between 5% and 25% in simulations, which is confirmed by first outdoor measurements.
The efficient and controllable synthesis, the detailed characterization, and the chemical postfunctionalization of polycarboxylated single-walled carbon nanotubes SWCNT(COOH)(n) are reported. This innovative covalent sidewall functionalization method is characterized by (a) the preservation of the integrity of the entire σ-framework of SWCNTs; (b) the possibility of achieving very high degrees of addition; (c) control of the functionalization degrees by the variation of the reaction conditions (reaction time, ultrasonic treatment, pressure); (d) the identification of conditions for the selective functionalization of semiconducting carbon nanotubes, leaving unfunctionalized metallic tubes behind; (e) the proof that the introduced carboxylic acid functionalities can serve as versatile anchor points for the coupling to functional molecules; and (f) the application of a subsequent thermal degradation step of the functionalized semiconducting tubes leaving behind intact metallic SWCNTs. Functional derivatives have been characterized in detail by means of Raman, UV-vis/nIR, IR, and fluorescence spectroscopy as well as by thermogravimetric analysis combined with mass spectrometry, atomic force microscopy, and zeta-potential measurements.
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