Brush-like structures emerge from stretching of long polymer chains, densely grafted on to the surface of an impermeable substrate. They arise due to the competition between conformational entropic elasticity of polymer chains and excluded volume interactions from the intra and interchain monomer repulsions. Recently, stimuli responsive polymer brush based soft materials have been developed to produce controllable and reversible large deformations of the host substrate. To understand these systems, and improve their functional properties, we study elastic stress distribution and surface stress-curvature relations of a neutral polymer brush grafted on to an elastic beam, made of a soft material. In the strongly stretched brush regime, we combine mean field theory from polymer physics with a continuum mechanics model and show that the residual stress variation is a quartic function of distance from the grafting surface, with maximum stress occurring at the grafted surface. Idealizing the brush as a continuum elastic surface layer with residual stress, we derive a closed form expression for surface stress and the surface elasticity of the layer as a function of brush parameters, such as graft density and molecular weight. The generalized continuum beam model accounts for the Young-Laplace and Ogden-Steigman curvature elasticity correction terms, and yields a surface stress-curvature relation, which contains existing relations in the literature as special cases. Further, we report experiments on a thermoresponsive random copolymer brush, Poly(N-isopropylacrylamide)-co-Poly(N,N-Dimethylacrylamide) (PNIPAm-co-PDMA) brush, grafted on one side of a plasticized poly(vinyl chloride) (pPVC) thin film. Estimated surface stress from measured curvature is on the order of −10 N/m, and it decreases gradually, and reversibly, with increasing ambient temperature from 15 • C to 55 • C.

This paper investigates the enhanced sensitivity to external perturbations through mode localization in a coupled resonant MEMS transducer device. An energy-based framework is developed to analytically study energy localization in the MEMS device by using a novel, electrostatically-induced stiffness perturbation. Specifically, we analyze the mode localization associated with eigenvalue veering phenomenon, resulting from a symmetry-breaking perturbation in a coupled two-resonators MEMS device. The measured mode shape sensitivities are compared with predictions made by both a simplified analytical model and a more detailed Simulink model. The mode shape sensitivity to perturbations is shown to be an order of magnitude higher than that of resonant frequency shifting. The sensitivity can be further increased by decreasing the coupling strength between the two resonators, but with a reduced dynamic range of the external perturbations.

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We study the stress distribution in a polymer brush material over a range of graft densities using molecular dynamics (MD) simulations and theory. Flexible polymer chains are treated as beads connected by nonlinear springs governed by a modified finitely extensible nonlinear elastic (FENE) potential in MD simulations. Simulations confirmed the quartic variation of the normal stress parallel to substrate, within the bulk of the brush, as predicted in our previous work, for low graft densities. However, in the high graft density regime, the Gaussian chain elasticity assumption is violated by finite extensibility effects (forceextension divergence) and the restriction to binary interaction among monomers is insufficient. This motivated us to extend a semi-analytical strong stretching mean field theory (SST) for polymer brushes, based on Langevin chains and a modified Carnahan-Starling equation of state to model monomer interactions. Our extended theory elucidates the stress and monomer density profiles obtained from MD simulations, as well as reproduces Gaussian chain results for small graft densities. A good agreement is observed between predictions of MD and Langevin chain SST for monomer density profile, end density profile and stress profile in high graft density regime, without fitting parameters (virial coefficients). Quantitative comparisons of MD results with various available theories suggest that excluded volume correlations may be important.

Recent studies have demonstrated mode localized resonant micro-electro-mechanical systems (MEMS) sensing devices with orders of magnitude improvement in sensitivity. Avoided crossings or eigenvalue veering is the physical mechanism exploited to achieve the enhancement in sensitivity of devices operating either in vacuum or in air. The mode localized MEMS devices are typically designed to be symmetric and use gap-varying electrostatic springs to couple motions of two or more resonators. The role of asymmetry in the design of devices and its influence on sensitivity is not fully understood. Furthermore, gap-varying electrostatic springs suffer from nonlinearities when gap variation between coupling plates becomes large due to mode localization, imposing limitations on the device performance. To address these shortcomings, this contribution has two principal objectives. The first objective is to critically assess the role of asymmetry in the device design and operation. We show, based on energy analysis, that carefully designed asymmetry in devices can lead to even higher sensitivities than reported in the literature. Our second objective is to design and implement linear, tunable, electrostatic springs, using shaped combs, which allow large vibration amplitudes of resonators thereby increasing the signal to noise ratio. We experimentally demonstrate linear electrostatic coupling in a two oscillator device. Our study suggests that a future avenue for progress in the mode localized resonant sensing technology is to combine asymmetric devices with tunable linear coupling designs.

Localization of normal modes is used in recent microelectromechanical systems (MEMS) technologies with orders of magnitude improvements in sensitivity. A pair of eigenvalues veer, or avoid crossing each other, as a single parameter of a vibrating system is varied. While it is well-known that the sensitivity (s) of modal amplitude ratio varies with strength of coupling (κ) as s ∝ κ −1 in the case of two identical coupled oscillators, recently, we showed that asymmetry α will also influence sensitivity according to s ∝ (ακ) −1 . Here, we show that further enhancements in sensitivity is possible in higher degrees of freedom (n) systems using energy analysis. In the case of n − 2 uniformly coupled oscillators embedded between two oscillators, we show that s ∝ α −1 κ 1−n , if the blocked resonance spectra of the embedded oscillators and the end oscillators are well-separated. We also show that asymmetric coupled oscillators also enhance linear range in addition to sensitivity when compared to their symmetric counterparts. We do not use a perturbation approach in our energy analysis; hence the sensitivity and linear range expressions derived have a wider range of accuracy. * srikanth@mech.ubc.ca † edmondc@ece.ubc.ca −0.2 −0.1

The application of a polymer brush in sensing, actuation, self-folding, among others acutely depends on the tuneable bending of a brush-grafted substrate caused by the stress in the brush. However, the stress in a stimuli-responsive brush has not been investigated. In this work, we study the stress in the stimuli-responsive planar polymer brushes of neutral water-soluble polymers with low to very high graft densities using strong stretching theory (SST). First, SST with the Langevin force-extension relation for a polymer chain is extended to the study of stimuli-responsive brushes. Stress profile and other properties of a Poly(N-isopropylacrylamide) (PNIPAm) brush are then obtained using the extended SST and an empirical Flory-Huggins parameter. The model predicts that the stress in a PNIPAm brush is inhomogeneous and compressive at all temperatures and graft densities. The resultant stress is predicted to increase in magnitude with increasing graft density. Moreover, it decreases in magnitude with an increase in temperature before plateauing in low graft density brushes. In contrast, its magnitude increases weakly with increasing temperature in high density brushes. This contrasting behavior is traced to the minimum in interaction free energy density vs polymer volume fraction curve for PNIPAm solution at a large volume fraction, and stiffening of chains due to finite extensibility. Furthermore, our results indicate that the ability to tune the resultant stress by changing temperature diminishes with increasing graft density.

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