Cross-disproportionation to combination ratios for CF2H and n-C3H7 radicals have been determined (the hydrogen acceptor radical is given first) to be A(n-C3H7,CF2H) = 0.30 2 0.01 and A(CF2H, n-C3H7) = 0.057 ? 0.006.
A new determination of the disproportionation/cornbination ratio for C2Fs and CZH, radicals gives a value of A(C2F,, C2H,) = 0.24 5 0.02, independent of temperature. The cross-combination ratio for the two radicals was found to increase with temperature and the significance of this is discussed in evaluating A.
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