Yb:CaYAlO(4) has been investigated spectroscopically and compared to better known Yb:CaGdAlO(4). It turns out that both materials show very similar spectroscopic parameters relevant to ultrafast lasers design. Employing single-mode fiber-coupled 400-mW laser diode at 976 nm we measured pulses as short as 43 fs, and broad tunability of 40 nm with a simple single-prism setup.
A detailed performance comparison of new interesting Yb-doped crystals in the same oscillator setup, with single-mode fiber-coupled diode laser pump is reported. We intended to assess the shortest pulses achievable with available SESAM technology, running a fair comparison with laser crystals Yb:KLuW, Yb:SSO, Yb:CALGO, Yb:CALYO and Yb:CaF2, very likely including the most promising choices for the next generation of commercial bulk ultrafast solid-state systems.
In this paper, we present the selective structuring of all three patterns (P1, P2 and P3) of a monolithic interconnection of CIS (Cu(In,Ga)(S,Se) 2 ) thin film solar cells by picosecond laser pulses at a wavelength of 1064 nm. We show results for single pulse ablation threshold values and line scribing of molybdenum films on glass (P1), CIS on molybdenum (P2) and zinc oxide on CIS (P3). The purposes of these processes are the p-type isolation (P1), cell interconnect (P2) and n-type isolation (P3), which are required for complete cell architecture. The half micron thick molybdenum back electrode can be structured with a process speed of more than 15 m/s at about 15 W average power without detectable residues and damage by direct induced laser ablation from the back side (P1). The CIS layer can be structured selectively down to the molybdenum at process speeds up to 1 m/s at about 15 W average power, due to the precision of direct laser ablation in the ultrashort pulse regime (P2). The ZnO front electrode layer is separated by clean trenches with straight side walls at process speeds of up to 15 m/s at about 10 W average power, as a result of indirect induced laser ablation (P3). A validation of functionality of all processes is demonstrated on CIS solar cell modules (30 × 30 cm 2 ). By replacing one state-of-the-art process by a picosecond laser process at a time, solar efficiencies could be increased for P1 and P2 and stayed on a similar level for P3. After an optimization of the patterning processes in the R&D pilot line of AVANCIS, we achieved a new record efficiency for an all-laser-patterned CIS solar module: 14.7% as best value for the aperture area efficiency of a 30 × 30 cm 2 sized CIS module was reached. Copyright
A new high-performance Yb:CaAlGdO(4) (Yb:CALGO) regenerative amplifier is demonstrated. Pumped by 116 W at ≈980 nm and seeded by means of a 92 fs oscillator, it generates as much as 36 W of average output power with chirped pulses, and 28 W with 217 fs compressed pulses at 500 kHz repetition rate. This corresponds to 56 μJ of pulse energy and 258 MW peak power. The compressed pulses have a time-bandwidth product of 0.69 and could be shortened further with an improved compressor setup.
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