NCSOIL is a submodel of a larger program NTRM (nitrogen‐tillage‐residue management). NCSOIL computes short‐term dynamics of carbon and nitrogen organics, ammonium, and nitrate which result from the processes of residue decomposition, mineralization, immobilization, nitrification, and denitrification. Both total and isotopic nitrogen are considered. NCSOIL is built on the concept of catenary sequence of heterogenous substrates. The active soil organic phase is divided in two pools which are dynamic, defined by their kinetic rate constants and their position in the model structure. Residues are defined in terms of their chemical or morphological nature. A double feedback loop in the carbon flow adjusts the rate of residue decomposition and the efficiency factor to the availability of inorganic nitrogen. NCSOIL was calibrated with, and its behavior contrasted against published and unpublished data from an experiment reported by Chichester et al. in Soil Science (see p. 455, vol. 120): “Relative Mineralization Rates of Indigenous and Recently Incorporated 15‐N labeled Nitrogen.” Experimental results of the Chichester et al. experiment were discussed in view of computer‐simulated flow rates and substrate concentrations.

Techniques to reliably calibrate computer models are needed before the models can be applied to help solve natural resource problems. The USDA‐ARS Root Zone Water Quality Model (RZWQM) is a comprehensive simulation model designed to predict hydrologic and chemical response, including potential for ground‐water contamination, of agricultural management systems. RZWQM Version 3.2 was calibrated and evaluated at sites in Iowa, Minnesota, Missouri, Nebraska, and Ohio as part of the Management Systems Evaluation Areas (MSEA) project and at a site near Sterling in northeastern Colorado. Soil horizon description and a description of the physical and hydraulic properties of the soil were required to initialize the model. Calibration for nutrient cycling involved adjusting the model coefficients for mineralization, infiltration, and denitrification. Initial N pool sizes were estimated using medium to long‐term computer simulations. Maximum N uptake rate, plant respiration, specific leaf area, and the effect of age at the time of propagule development and senescence were used to calibrate the plant production and yield component. To match the observed results for soil water, N, and plant growth, an iterative approach for calibrating the model was followed. When done methodically, total biomass estimates were within 5%, yield estimates were within l0%, and N uptake was within 20% of field measurements. Calibration of the C and N dynamics module produced results that were generally within 20 to 50 kg ha−1 of measured values for soil profile NO−3‐N. Independent evaluations of the calibrated model focused on four indicator output variables related to plant growth—total biomass, yield, N uptake, and N in the soil profile. Predictions matched the observed data in most cases. The crop model is very sensitive to plant N content. Even small errors in simulating N uptake levels can result in substantial errors in estimates of yield and total aboveground biomass. The model predicted biomass and yield well on irrigated and most dryland management systems and adequately simulated crop variables at various positions along the landscape.

On agricultural lands, animal waste disposal as fertilizer has been practiced since the beginning of agriculture. However, the practice has been an environmental concern in recent years due to over disposal of animal waste in some instances. This study evaluated soil NO3 response to beef‐manure application on a corn (Zea mays L.) field and tested the Root Zone Water Quality Model (RZWQM) for manure management. The experiment site was located in Northeastern Colorado on a silage‐corn field with a history of fertilization with beef manure every fall after corn harvest. To study the residual effect of long‐term manure application, 582 kg ha‐1 of manure‐N was applied to the east side of the field in the Fall of 1993, 1994, and 1995, while the west side received manure in 1993 only. Average silage‐corn yields from the west site were 25.4, 31.9, and 22.5 Mg ha‐1 for 1994, 1995, and 1996, respectively, which were not significantly different from that harvested from the east site (25.1, 30.9, and 24.3 Mg ha‐1, respectively). Average soil NO3 concentrations decreased significantly from 14.9 to 8.5 mg N kg‐1 in the top 30 cm of soil, and from 5.4 to 3.7 mg N kg‐1 in the 30‐ to 60‐cm soil profile after stopping manure application. No significant difference in soil NO3 concentrations between the manured and not‐manured sites was found below 60 cm. Average plant N uptake ranged from 140 to 362 kg N ha‐1 and was not significantly different between the two sites. The RZWQM was calibrated on the basis of the measured silage‐corn yield and plant N uptake, and was then used to predict soil NO3 concentration and total water storage in the soil profile. Generally, the calibrated model provided adequate predictions for both NO3 and soil water content with r2 > 0.83. The model was further used to evaluate alternative scenarios of manure and water management.

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The high spatial variability of nitrate concentrations in ground water of many regions is thought to be closely related to spatially-variable leaching rates from agricultural activities. To clarify the relative roles of the different nitrate leaching controlling variables under irrigated agriculture in northeastern Colorado, we conducted an extensive series of leaching simulations with the NLEAP model using best estimates of local agricultural practices. The results of these simulations were then used with GIS to estimate the spatial variability of leachate quality for a 14,000 ha area overlying the alluvial aquifer of the South Platte River. Simulations showed that in the study area, differences in soil type might lead to 5-10 kg/ha of N variation in annual leaching rates while variability due to crop rotations was as much as 65 kg-N/ha for common rotations. Land application of manure from confined animal feeding operations may account for more than 100 kg-N/ha additional leaching. For a selected index rotation, the simulated nitrogen leaching rates across the area varied from 10 to 299 kg/ha and simulated water volumes leached ranged from 13 to 76 cm/yr depending on soil type, irrigation type, and use of manure. Resulting leachate concentrations of 3.5-140 mg/l NO3 as N were simulated. Land application of manure was found to be the most important factor determining the mass flux of nitrate leached and the combination of sprinkler irrigation and manure application yields the highest leachate concentrations. (KEY TERMS: nonpoint source pollution; pollution modeling; agricultural hydrology; NLEA.P; GIS; irrigation; spatial variability.) 1Paper

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